Negative Electrode Composite Material for Lithium Ion Battery Safety

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Solution Overview

Problem

Lithium ion batteries face challenges in improving safety performance while maintaining high energy density, as existing methods like inorganic insulating coatings increase processing complexity and reduce pass rates, and affect volume energy density.

Innovation Solution

A negative electrode composite material is developed with a specific surface area ratio of 1-7, incorporating a metal oxide on the active material surface, prepared using a sol-gel method, which enhances safety and cycle performance without significantly impacting energy density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an inorganic insulating coating is introduced to improve safety performance, then safety performance is improved, but device complexity and processing difficulty increase

Engineering Contradiction:
Improvesafety performanceVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the safety function and active material function into a single composite material. The metal oxide particles are dispersed within the active material matrix, creating an integrated structure that provides both electrochemical activity and safety protection without requiring separate coating layers or additional processing steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a composite material consisting of metal oxide particles dispersed in an active material matrix. This composite structure inherently provides both the electrochemical functionality of the active material and the safety characteristics of the metal oxide, eliminating the need for separate inorganic insulating coating layers.

Inventive Principle:
Principle #40Composite materials

2Reliability

If an inorganic insulating coating is introduced to improve safety performance, then safety performance is improved, but manufacturing efficiency decreases

Engineering Contradiction:
Improvesafety performanceVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent combines the safety function and active material function into a single composite material. The metal oxide particles are dispersed within the active material matrix, creating an integrated structure that provides both electrochemical activity and safety protection without requiring separate coating layers or additional processing steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The composite material structure provides safety functionality inherently through the dispersed metal oxide particles within the active material matrix itself, rather than requiring external coating processes. The active material serves dual purposes: electrochemical function and structural integration of safety features.

Inventive Principle:
Principle #25Self-service

3Reliability

If an inorganic insulating coating is introduced to improve safety performance, then safety performance is improved, but volume energy density decreases

Engineering Contradiction:
Improvesafety performanceVSAvoidvolume energy density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent applies safety functionality locally through dispersed metal oxide particles within the active material matrix rather than through a continuous coating layer. This localized distribution provides safety protection at specific points where needed while maintaining the overall volume available for energy-storing active material.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses a composite material consisting of metal oxide particles dispersed in an active material matrix. This composite structure inherently provides both the electrochemical functionality of the active material and the safety characteristics of the metal oxide, eliminating the need for separate inorganic insulating coating layers.

Inventive Principle:
Principle #40Composite materials

4Reliability

If an inorganic insulating coating is introduced to improve safety performance, then safety performance is improved, but electrode pass rate decreases

Engineering Contradiction:
Improvesafety performanceVSAvoidelectrode pass rate
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent combines the safety function and active material function into a single composite material. The metal oxide particles are dispersed within the active material matrix, creating an integrated structure that provides both electrochemical activity and safety protection without requiring separate coating layers or additional processing steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The composite material structure provides safety functionality inherently through the dispersed metal oxide particles within the active material matrix itself, rather than requiring external coating processes.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material improves lithium ion battery safety and cycle performance, maintains high energy density, and withstands thermal shock and puncturing tests effectively.

Implementation Method 1

adding an alkoxide of a metal oxide to a pre-acidified second solvent to prepare a sol-gel solution

Methodology Applied
Scientific EffectSol-gel method: Sol

Implementation Method 2

adding an alkoxide of a metal oxide to a pre-acidified second solvent to prepare a sol-gel solution

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

adding an alkoxide of a metal oxide to a pre-acidified second solvent to prepare a sol-gel solution

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

drying and performing heat treatment under an inert gas to obtain a negative electrode composite material

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS11322743B2Negative electrode composite material and preparation method thereof and lithium ion battery
Publication Date: 2022.05.03 NINGDE AMPEREX TECHNOLOGY LTD

AI summary

The present application relates to a negative electrode composite material and preparation thereof and a lithium ion battery. The negative electrode composite material comprises an active material, a metal oxide on the surface of the active material, wherein the ratio of the specific surface area of the negative electrode composite material to the specific surface area of the active material is 1-7. The present application improves the volume energy density and safety performance of a lithium ion battery by selecting a ratio of a specific surface area of the negative electrode composite material to the active material.