Negative Electrode Layer Layout for Better Electrolyte Impregnation
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Solution Overview
Problem
In cylindrical rechargeable batteries, the increased thickness of the active material layer leads to a non-moisture area in the center portion of the electrode assembly, resulting in decreased battery performance and shortened electrode plate lifespan.
Innovation Solution
A negative electrode with a strip-shaped base material and an active material layer comprising an aligned part and a non-aligned part, where the aligned part is positioned to minimize the non-moisture area, allowing the electrolytic solution to move smoothly and maintain high capacity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If the thickness of the active material layer is increased to achieve high capacity, then the battery capacity is improved, but a non-moisture area is generated in the center portion of the electrode assembly
Solution Approach 1:
The active material layer is segmented into multiple layers with different thicknesses. The center portion has a thinner active material layer while the outer portions have thicker layers, allowing electrolyte to penetrate the center area effectively while maintaining high overall capacity through the thicker outer layers.
Solution Approach 2:
Different regions of the electrode assembly are given different local qualities in terms of active material layer thickness. The center portion receives a thinner layer to ensure electrolyte penetration, while outer portions receive thicker layers to maximize capacity, creating a non-uniform thickness distribution optimized for both impregnation and capacity.
2Quantity of substance
If the active material layer is made thicker to increase capacity, then the battery capacity is improved, but the electrolytic solution cannot moisten the center portion effectively
Solution Approach 1:
The active material layer is divided into multiple layers with varying thicknesses. The thinner layer at the center facilitates electrolyte penetration, while the thicker outer layers provide high capacity, resolving the contradiction between penetration ease and capacity.
Solution Approach 2:
The solution transitions from a uniform thickness approach to a dimensionally varied thickness profile across the electrode radius. This dimensional variation in layer thickness enables simultaneous achievement of good electrolyte penetration in the center and high capacity in the outer regions.
3Quantity of substance
If the active material layer thickness is increased for high capacity, then the capacity is improved, but the electrode plate lifespan is decreased
Solution Approach 1:
The electrode plate is given non-uniform local quality with thinner active material layer at the center and thicker layers at outer portions. This prevents severe non-moisture phenomena that would otherwise occur in uniformly thick electrodes, thereby extending electrode plate lifespan while maintaining high overall capacity.
Solution Approach 2:
The invention converts the potential harm of thick active material layers (which cause non-moisture areas and reduce lifespan) into a benefit by strategically placing thinner sections at the center where electrolyte penetration is most difficult, while retaining thick high-capacity sections at outer portions where they are most effective.
Data Source
AI summary
A negative electrode for a rechargeable battery includes a base material having a strip shape, a length of the base material in a first direction being relatively shorter than a width of the base material in a second direction intersecting the first direction, and an active material layer on the base material and including an aligned part and a non-aligned part, the active material arranged in the first direction in an order of the non-aligned part, the aligned part, and the non-aligned part, in which the aligned part includes a lower layer and an upper layer stacked on the base material, and alignment directions of the lower layer and the upper layer are different from each other.


