Nematic Liquid Crystal Composition for Low Viscosity and High Speed

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Solution Overview

Problem

Existing liquid crystal compositions with positive dielectric anisotropy fail to achieve sufficiently low viscosity without compromising refractive-index anisotropy and nematic phase-isotropic liquid phase transition temperature.

Innovation Solution

A liquid crystal composition comprising specific fluorobenzene derivatives represented by General Formulae (LC0-1) to (LC5), which include alkyl groups and cyclohexane or benzene rings with specific substitutions, ensuring a positive dielectric anisotropy and low viscosity while maintaining stability across a wide temperature range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If liquid crystal compositions with positive dielectric anisotropy are used to achieve horizontal-alignment-type displays, then the display mode versatility is improved, but the viscosity cannot be reduced sufficiently

Engineering Contradiction:
Improvedisplay mode versatilityVSAvoidviscosity
Core Design Contradiction:
Adaptability or versatilityVSForce

Solution Approach 1:

The patent employs a composite liquid crystal composition comprising multiple components: a first liquid crystal compound (cyclic carbonate derivative), a second liquid crystal compound (fluorinated cyclic carbonate derivative), and a third liquid crystal compound (aromatic compound with specific molecular structure). This composite approach allows optimization of overall composition properties to achieve both low viscosity and positive dielectric anisotropy, resolving the contradiction between versatility and viscosity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically adjusts molecular structure parameters of the liquid crystal compounds, specifically incorporating fluorine atoms at predetermined positions in the cyclic carbonate rings and optimizing the aromatic substituent patterns. These parameter changes enable reduction of intermolecular forces and viscosity while maintaining the positive dielectric anisotropy required for horizontal-alignment display modes.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If the dielectric anisotropy is increased to enable low-voltage drive, then the drive voltage is reduced, but the response speed may be affected

Engineering Contradiction:
Improvedrive voltageVSAvoidresponse speed
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent optimizes the balance between dielectric anisotropy and rotational viscosity by carefully selecting the molecular structures of the three liquid crystal compounds. The fluorinated cyclic carbonate derivatives provide high dielectric anisotropy for low-voltage operation, while the specific aromatic compounds contribute to maintaining appropriate rotational viscosity for fast response, achieving both low drive voltage and high response speed simultaneously.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces fluorine atoms at specific local positions (predetermined positions) in the molecular structures of the cyclic carbonate derivatives. This localized modification enhances dielectric anisotropy in specific molecular regions without significantly increasing overall molecular size or rotational viscosity, enabling low-voltage drive while preserving response speed.

Inventive Principle:
Principle #3Local quality

3Speed

If the liquid crystal composition is optimized for high-speed response with low rotational viscosity, then the response speed is improved, but the operating temperature range may be reduced

Engineering Contradiction:
Improveresponse speedVSAvoidoperating temperature range
Core Design Contradiction:
SpeedVSTemperature

Solution Approach 1:

The patent uses a composite composition of three different liquid crystal compounds with complementary properties. The cyclic carbonate derivatives provide low rotational viscosity for fast response, while the aromatic compounds with specific substituent patterns contribute to stabilizing the nematic phase across a wide temperature range. This composite approach balances response speed and thermal stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent merges the functional advantages of different liquid crystal compound classes: the fluorinated cyclic carbonate derivatives contribute low viscosity and high dielectric anisotropy, while the aromatic compounds provide thermal stability and wide operating temperature range. By combining these components in specific ratios, the composition achieves both high-speed response and broad temperature operation.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves a high dielectric anisotropy with low viscosity and rotational viscosity, exhibiting stable liquid-crystal properties over a wide temperature range, enabling low-voltage drive and high-speed response in liquid crystal displays.

Implementation Method 1

a liquid crystal composition having a positive dielectric anisotropy (Δε) which can be suitably used as a material for electro-optical liquid crystal displays

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

the refractive-index anisotropy (An) of the liquid crystal composition for each individual display element

Methodology Applied
Scientific EffectRefractive-index anisotropy: Birefringence

Data Source

PatentEP2835410B1Nematic liquid crystal composition
Publication Date: 2017.10.04 DIC CORP
  • EP2835410B1 patent drawing
  • EP2835410B1 patent drawing
  • EP2835410B1 patent drawing

AI summary

The nematic liquid crystal composition according to the present invention is used for, for example, producing a liquid crystal display elementused in TN mode, OCBmode, ECBmode, IPSmode, or VA-IPS mode. The liquid crystal composition has a positive dielectric anisotropy and allows reductions in refractive-index anisotropy and nematic phase-isotropic liquid phase transition temperature and an increase in the lower limit temperature of a nematic phase to be suppressed. As a result, the liquid crystal composition has a sufficiently low viscosity without deteriorating the temperature range of a nematic phase. The liquid crystal composition allows high-speed response and high display quality to be realized, suppresses faulty display, and is suitably used as a practical liquid crystal composition.