Exhaust Gas Purification Catalyst with Neodymium Gradient

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Solution Overview

Problem

Existing exhaust gas purification catalysts are inadequate for efficiently purifying hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at low temperatures and struggle with responsiveness and durability, especially when transitioning from low-temperature to high-temperature exhaust gas conditions.

Innovation Solution

An exhaust gas purification catalyst with a three-dimensional structure containing palladium, divided into regions with varying neodymium concentrations, where the first region has a higher neodymium concentration than the second region, and both regions include neodymium-containing zirconium oxides to enhance rhodium distribution and catalytic activity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a conventional exhaust gas purification catalyst is used, then the catalyst structure is simple and easy to manufacture, but the catalytic responsiveness is low and purification efficiency at low temperatures is insufficient

Engineering Contradiction:
Improvecatalyst structure simplicityVSAvoidcatalytic responsiveness
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The catalyst is divided into multiple regions with different neodymium concentrations: a first region with higher neodymium concentration and a second region with lower neodymium concentration. This segmentation allows different regions to perform different functions - the first region provides high catalytic activity at low temperatures, while the second region maintains overall catalyst stability and structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the catalyst are assigned different local compositions - the first region contains a higher concentration of neodymium for enhanced low-temperature activity, while the second region has a lower concentration for structural stability. This local quality differentiation optimizes overall catalyst performance across varying temperature conditions.

Inventive Principle:
Principle #3Local quality

2Loss of energy

If the catalyst operates at low temperatures, then energy consumption is reduced, but purification efficiency of HC, CO, and NOx is insufficient

Engineering Contradiction:
Improveenergy consumptionVSAvoidpurification efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The catalyst composition is modified by introducing neodymium at varying concentrations in different regions. This parameter change in chemical composition enables the catalyst to maintain high purification efficiency at low operating temperatures, eliminating the need for high energy input while achieving effective exhaust gas treatment.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If the catalyst is exposed to sudden high-temperature exhaust gas, then the exhaust gas temperature increases rapidly, but the catalyst cannot immediately purify the exhaust gas due to thermal shock

Engineering Contradiction:
Improveexhaust gas temperatureVSAvoidcatalyst durability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The catalyst structure incorporates a second region with lower neodymium concentration that provides thermal stability and structural support. This region acts as a buffer that protects the catalyst structure from sudden thermal shocks when high-temperature exhaust gas is introduced, maintaining catalyst integrity and continuous purification capability.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

4Productivity

If the catalyst uses high concentrations of precious metals, then purification activity is improved, but cost increases and catalyst complexity increases

Engineering Contradiction:
Improvepurification activityVSAvoidcatalyst composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

Instead of uniformly distributing precious metals throughout the catalyst, the invention concentrates neodymium in the first region where it is most needed for low-temperature activity, while reducing its concentration in the second region. This localized quality optimization maintains high purification activity while reducing overall precious metal content and simplifying catalyst composition.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst effectively purifies HC, CO, and NOx at low temperatures, demonstrating improved responsiveness and durability, capable of handling sudden changes in exhaust gas temperature and volume, with a high purification rate and long-term NOx removal efficiency.

Implementation Method 1

a region containing palladium, the region being provided on a three-dimensional structure; and a first region and a second region being provided on the region containing palladium... capable of purifying hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) in exhaust gas at low temperatures

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS11143072B2Exhaust gas purification catalyst and exhaust gas purification method using the same
Publication Date: 2021.10.12 UMICORE SHOKUBAI JAPAN CO LTD
  • US11143072B2 patent drawing
  • US11143072B2 patent drawing

AI summary

In order to provide an exhaust gas purification catalyst capable of purifying hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas at low temperatures, the exhaust gas purification catalyst according to the present invention includes: a region (2) containing palladium on a three-dimensional structure (1), and a first region (3) and a second region (4) provided on the region (2) in order from an inflow side of exhaust gas to an outflow side of exhaust gas. The concentration of neodymium contained in the first region (3) is higher than the concentration of neodymium contained in the second region (4).