Nested Nanoemulsion for Oxidative Stability

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Solution Overview

Problem

Existing methods for encapsulating oxidisable lipids like omega-3 fatty acids in food products face challenges with oxidative stability, heat stability, and the need to avoid antioxidants, which can cause adverse reactions in complex food systems, leading to flavor and texture issues and reduced shelf life.

Innovation Solution

An oil-in-water emulsion is created where core lipid droplets are coated with nanoemulsion droplets, with the surface lipid coated with protein, enhancing oxidative stability and heat stability, and allowing for targeted antioxidant placement to prevent adverse reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxidisable lipids are encapsulated using conventional emulsion methods with proteins or polysaccharides, then the lipid is protected from direct oxygen contact, but the emulsion remains vulnerable to oxidation and requires additional antioxidants that may cause adverse reactions

Engineering Contradiction:
Improveoxidative stabilityVSAvoidadverse reactions from antioxidants
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies nested doll by creating a multi-layered protective structure where core lipid droplets are coated with nanoemulsion droplets, and each nanoemulsion droplet comprises a surface lipid coated with protein. This nested arrangement provides multiple barriers against oxidation without requiring additional antioxidants.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent uses composite materials by combining different substances (proteins, lipids, and oxidisable core lipids) into a structured emulsion system where each component contributes specific protective functions, creating a synergistic effect that enhances oxidative stability without adverse reactions.

Inventive Principle:
Principle #40Composite materials

2Reliability

If antioxidants are incorporated to protect oxidisable lipids, then oxidation is reduced, but pro-oxidant activity may occur in complex food systems leading to flavor and texture deterioration

Engineering Contradiction:
Improveoxidative stabilityVSAvoidflavor and texture deterioration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts the need for antioxidants from the system by creating a physical barrier structure that prevents oxidation without requiring chemical antioxidants. The nested emulsion structure itself provides the protective function that would otherwise require separate antioxidant additives.

Inventive Principle:
Principle #2Taking out (Extraction)

3Quantity of substance

If fish oil is incorporated into food products to increase omega-3 intake, then nutritional benefits are improved, but oxidative damage occurs quickly affecting flavor, aroma, texture and shelf life

Engineering Contradiction:
Improveomega-3 LC PUFA contentVSAvoidshelf life
Core Design Contradiction:
Quantity of substanceVSDuration of action of stationary object

Solution Approach 1:

The patent protects fish oil by nesting it within core lipid droplets that are further coated with nanoemulsion droplets containing protein. This multi-layered nested structure provides robust protection against oxidation, extending shelf life while maintaining omega-3 content.

Inventive Principle:
Principle #7Nested doll (Nesting)

4Device complexity

If a simple protein coating is used to encapsulate oxidisable lipids, then the structure is simple, but the emulsion is still vulnerable to oxidation and requires antioxidants

Engineering Contradiction:
Improveencapsulation structureVSAvoidoxidative stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent enhances the simple protein coating concept by nesting nanoemulsion droplets within the emulsion structure. Each nanoemulsion droplet comprises a surface lipid coated with protein, creating a more complex but effective multi-layered protective system that eliminates the need for additional antioxidants.

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The emulsion demonstrates high oxidative stability and heat stability, reducing lipid oxidation and maintaining flavor and texture, thus extending shelf life and improving the palatability of fortified foods.

Implementation Method 1

encapsulate the lipid so as to reduce its contact with oxygen, trace metals and other substances that attack the double bonds and other susceptible locations of the lipid

Methodology Applied
Scientific EffectEncapsulation:

Implementation Method 2

oil-in-water emulsion that protects the lipid phase of the emulsion from oxidative damage by coating the lipids with nanoemulsion droplets

Methodology Applied
Scientific EffectEmulsion: Emulsion

Data Source

PatentUS8993019B2Emulsion
Publication Date: 2015.03.31 MASSEY UNIVERSITY
  • US8993019B2 patent drawing
  • US8993019B2 patent drawing
  • US8993019B2 patent drawing

AI summary

The invention relates to the encapsulation of oxidizable lipids. In particular, the invention provides an oil-in-water emulsion comprising droplets of a core lipid coated with nanoemulsion droplets, wherein the nanoemulsion droplets comprise a surface lipid coated with protein. The emulsions of the invention provide an oxidatively stable form of the lipid, which can be added to foods and cosmetics requiring a long shelf-life.