Networked Silicone Mechanical Strength via Hindered Crosslinking

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Solution Overview

Problem

Conventional silicone networks exhibit weak mechanical properties, such as low tensile strength, tear strength, and modulus, which limits their applications despite their advantages in thermal and oxidative stability and optical transmission.

Innovation Solution

A composition comprising a hindered organosilicon compound, a crosslinking compound, and optionally a catalyst, where the hindered organosilicon compound has a specific siloxane moiety structure that allows for crosslinking, resulting in a networked silicone with improved mechanical properties and maintained optical stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional silicone networks are used, then thermal and oxidative stability and optical transmission are maintained, but mechanical properties such as tensile strength, tear strength, and modulus are weak

Engineering Contradiction:
Improvemechanical propertiesVSAvoidoptical stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a composite network structure by combining organopolysiloxane chains with crosslinking agents forming siloxane bonds. This composite approach integrates the thermal and oxidative stability of silicones with enhanced mechanical strength through the crosslinked network, resolving the contradiction between maintaining optical stability and improving mechanical properties

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical structure parameters of silicone networks by introducing specific crosslinking agents and controlling crosslinking density. By changing the molecular architecture from linear to crosslinked networks and adjusting crosslinking parameters, the patent simultaneously improves mechanical strength while preserving the optical stability characteristic of silicones

Inventive Principle:
Principle #35Parameter changes

2Strength

If reinforcing fillers are added to improve mechanical robustness, then tensile strength and tear strength increase, but optical properties are compromised

Engineering Contradiction:
Improvemechanical robustnessVSAvoidoptical transmission
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent replaces the mechanical reinforcement approach (adding physical fillers that scatter light) with a chemical reinforcement approach (forming molecular-level crosslinks). This substitution achieves mechanical robustness through covalent bonding in the polymer network rather than through physical filler addition, thereby maintaining optical transmission properties

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent applies reinforcement at the molecular level through crosslinking rather than adding macroscopic fillers. The crosslinks are distributed locally throughout the polymer chains, providing mechanical strength without introducing light-scattering particles that would compromise optical transmission

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the mechanical properties of networked silicones, including tensile strength, tear strength, and modulus, while preserving low-loss and stable optical transmission, making them suitable for diverse applications.

Implementation Method 1

a crosslinking compound... reacting the hindered organosilicon compound (A) and the crosslinking compound (B)... to give the networked silicone

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentUS11981815B2Networked silicones and related compositions, methods, and compounds
Publication Date: 2024.05.14 DOW SILICONES CORP
  • US11981815B2 patent drawing

AI summary

A networked silicone is disclosed. The networked silicone comprises crosslinked strands of hindered organosilicon compounds. A composition for preparing the networked silicone is also disclosed, and comprises (A) a hindered organosilicon compound, (B) a crosslinking compound, and optionally (C) a catalyst. Additionally, a method of preparing the networked silicone is disclosed, and comprises reacting the hindered organosilicon compound (A) and the crosslinking compound (B), optionally in the presence of the catalyst (C), to give the networked silicone. A reaction product comprising the networked silicone is also disclosed. The reaction product is prepared from the composition and/or in accordance with the method, and may be a cured product. Additionally, a composite article and a method of forming the same are disclosed. The composite article is formed by disposing a networked silicone composition on the substrate and curing the networked silicone composition, thereby preparing the composite article.