Neutral Atom Beam Surface Treatment for Semiconductor Interconnects

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Solution Overview

Problem

The CMP process causes damage to the surface of dielectric layers in semiconductor structures, particularly those with ultra-low-k dielectric materials, leading to reliability issues in interconnects, and the lack of alloy element segregation on copper surfaces reduces electromigration resistance.

Innovation Solution

Applying a neutral atom beam treatment to densify the dielectric layer surface and create point defects on the copper surface, promoting the segregation of alloy elements and enhancing electromigration resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a chemical-mechanical planarization (CMP) process is used to form metallic conductors in dielectric layers, then the interconnect structure can be formed with desired planarity, but the surface of the dielectric layer becomes damaged, reducing reliability

Engineering Contradiction:
Improveplanarity of interconnect structureVSAvoidreliability of interconnects
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A surface treatment process acts as an intermediary step between CMP and subsequent processing. This treatment process repairs CMP-induced damage to the dielectric layer surface without removing the planarity achieved by CMP, thereby restoring reliability while preserving manufacturing precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical polishing action of CMP with a chemical or physical vapor deposition-based surface treatment process. This substitution allows for repair of surface damage without the mechanical forces that cause degradation, particularly for ultra-low-k dielectric materials.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If alloy elements are introduced into copper interconnects to enhance electromigration resistance, then EM resistance should improve, but the alloy elements do not segregate onto the Cu surface, degrading the expected EM resistance enhancement

Engineering Contradiction:
Improveelectromigration resistanceVSAvoidalloy element segregation
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The surface treatment process is applied preliminarily to create surface conditions (such as point defects or modified surface energy) that promote subsequent segregation of alloy elements to the Cu surface. This preliminary action sets the stage for achieving the desired composition stability and EM resistance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The surface treatment process changes physical or chemical parameters of the Cu surface (such as surface energy, defect density, or crystal structure) to create favorable conditions for alloy element segregation. These parameter changes enable the alloy elements to migrate to the surface where they can provide the intended EM resistance enhancement.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treatment effectively remedies CMP-induced damage by densifying the dielectric layer and promoting alloy element segregation, thereby improving the reliability and electromigration resistance of interconnects.

Implementation Method 1

the surface treatment is a neutral atom beam treatment

Methodology Applied
Scientific EffectNeutral atom beam treatment: Ion Beam

Implementation Method 2

create point defects on the copper surface, promoting the segregation of alloy elements

Methodology Applied
Scientific EffectNeutral atom beam treatment: Ion Beam

Data Source

PatentUS10276503B2Surface treatment for semiconductor structure
Publication Date: 2019.04.30 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US10276503B2 patent drawing
  • US10276503B2 patent drawing
  • US10276503B2 patent drawing

AI summary

A method includes forming a dielectric layer and forming a metallic conductor at least partially in the dielectric layer. Formation of the metallic conductor at least partially in the dielectric layer includes performing a planarization process. The method further includes treating respective surface areas of the dielectric layer and the metallic conductor, after the planarization process, to modify the respective surface areas of the dielectric layer and the metallic conductor. In one example, the surface treatment is a neutral atom beam treatment.