Continuous Neutralization Ring Line for Polymer Temperature Control

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Solution Overview

Problem

The existing neutralization processes for producing water-absorbing polymers are inefficient due to logistical challenges and heat-related issues in continuous neutralization, leading to premature polymerization and equipment blockages.

Innovation Solution

A device for continuous neutralization featuring a ring line with heat exchangers, multiple feed lines for educts like caustic soda and acrylic acid, and a pump system to manage temperature and prevent overheating, utilizing a buffer container and Venturi tube design to minimize peak temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If continuous neutralization is implemented to improve productivity, then productivity increases, but temperature peaks cause premature polymerization and equipment blockages

Engineering Contradiction:
Improvecontinuous neutralization throughputVSAvoidprocess stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The neutralization process is divided into multiple stages with sequential addition of educts through separate feed lines. The ring line configuration creates distinct zones for mixing and cooling, segmenting the heat generation and allowing controlled temperature management throughout the continuous process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The ring line acts as an intermediary cooling pathway between the feed lines and the discharge point. By circulating the neutralization mixture through the ring line with heat exchangers, the system provides intermediate cooling that prevents temperature peaks while maintaining continuous operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Temperature

If multiple feed lines are used to control temperature, then temperature control improves, but device complexity increases

Engineering Contradiction:
Improvetemperature control precisionVSAvoidnumber of feed lines and ring line configuration
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The ring line serves multiple functions simultaneously: it is a feed line for educt introduction, a cooling channel with heat exchangers, a mixing zone, and a discharge pathway. This multi-functionality reduces the need for separate dedicated components for each function, thereby limiting the increase in device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent combines the cooling function with the feed line and discharge line by forming a ring line configuration. Instead of having separate cooling exchangers and feed lines, the system merges these functions into a single integrated ring structure that performs multiple operations in sequence.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device effectively controls temperature peaks, preventing premature polymerization and reducing logistical efforts, thereby enhancing the economic efficiency and continuity of the polymerization process.

Implementation Method 1

at least one heat exchanger W in the ring line R

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

Due to the heat of neutralization, the temperature rises to 95°C

Methodology Applied
Scientific EffectHeat removal: Cooling

Implementation Method 3

a pump P

Methodology Applied
Scientific EffectPumping: Pump

Implementation Method 4

at least one first feed line Z 1 into the ring line R, at least one second feed line Z 2 into the ring line R

Methodology Applied
Scientific EffectMixing: Stirring

Data Source

PatentEP2360138B1Apparatus for cyrrying out a continuous neutralization process
Publication Date: 2018.10.31 BASF SE
  • EP2360138B1 patent drawingFigure 1

AI summary

Neutralization procedure comprises partially neutralizing at least an ethylenically unsaturated carboxylic acid compound with a base, where the neutralization takes place in a continuous process and the neutralized solution is at less than 70[deg]C. Independent claims are included for: (1) a procedure for production of water-absorbing polymer comprising a neutralization procedure; and (2) a device for continuous neutralization comprising a circular pipe (R), at least a first supply pipe (Z 1) and second supply pipe (Z 2) in the circular pipe, at least a heat exchanger (W 1) in the circular pipe, where the heat exchanger flows directly behind the supply pipes, at least a conduit (A), which flows directly behind the heat exchanger, a pump (P) and optionally a container (B) between the heat exchanger and the conduit.