Ni-Mg Bonding Alloy for Aluminum-Steel Interfaces

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Solution Overview

Problem

Aluminum materials face challenges in bonding with non-aluminum metals like steel, copper, and titanium due to the formation of fragile intermetallic compounds, which degrades bondability and requires precise diffusion annealing conditions, limiting their use in applications such as power modules and structural components in vehicles.

Innovation Solution

An Ni—Mg alloy with a specific magnesium content is developed, which enhances pressure weldability, diffusion bondability, and brazability to both non-aluminum metals and aluminum, reducing the growth of intermetallic compounds and maintaining bonding strength by reducing aluminum oxide at the interface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If aluminum is directly bonded to non-aluminum metals such as steel, copper, or titanium, then bonding can be achieved, but fragile intermetallic compounds form which degrade bondability and require precise diffusion annealing conditions

Engineering Contradiction:
Improvebonding strengthVSAvoiddiffusion annealing condition control
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces an Ni-Mg alloy layer as an intermediary between aluminum and non-aluminum metals. This intermediate layer prevents direct contact between aluminum and metals like steel, copper, or titanium, thereby avoiding the formation of fragile intermetallic compounds while maintaining good bondability to all materials involved.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical composition parameters of the bonding layer by specifying an Ni-Mg alloy with Mg content of 0.08-0.90 mass%. This parameter change in alloy composition alters the diffusion behavior and intermetallic compound formation characteristics, enabling broader and more relaxed diffusion annealing conditions while maintaining bonding reliability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If an aluminum layer and nickel layer are directly bonded together, then excellent bondability is achieved, but Al-Ni intermetallic compounds grow excessively which significantly degrades bondability

Engineering Contradiction:
ImprovebondabilityVSAvoidbonding strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The Ni-Mg alloy serves as a modified intermediary layer between aluminum and nickel. The magnesium component in the alloy controls the diffusion rate and intermetallic compound growth, preventing excessive Al-Ni intermetallic formation while maintaining the excellent bondability characteristics of the Al-Ni system.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By adjusting the Mg content in the nickel-based alloy to 0.08-0.90 mass%, the patent optimizes the diffusion characteristics and intermetallic compound formation kinetics. This parameter modification allows the system to maintain good bondability while suppressing excessive intermetallic growth that would otherwise degrade bonding strength.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If aluminum and copper are diffusion-bonded together, then bonding can be achieved, but a highly fragile intermetallic compound is produced which prevents direct bonding

Engineering Contradiction:
ImprovebondabilityVSAvoidintermetallic compound fragility
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The Ni-Mg alloy layer acts as an intermediary between aluminum and copper, preventing direct Al-Cu contact and the formation of highly fragile Al-Cu intermetallic compounds. The alloy maintains good bondability to both aluminum and copper while avoiding the formation of brittle compounds at the interface.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If pressure welding and diffusion bonding are used to bond aluminum to non-aluminum metals, then bonding can be achieved, but the process requires precise control of diffusion annealing conditions to prevent excessive intermetallic compound growth

Engineering Contradiction:
Improvebonding strengthVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent specifies an Ni-Mg alloy with Mg content of 0.08-0.90 mass%, which modifies the diffusion characteristics and intermetallic compound formation kinetics. This parameter optimization enables the bonding process to proceed under broader and more relaxed diffusion annealing conditions, reducing manufacturing complexity while maintaining bonding quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The Ni-Mg alloy intermediate layer simplifies the manufacturing process by decoupling the bonding interface from direct Al-non-aluminum metal contact. This intermediary structure allows for more flexible and less precise control of diffusion annealing parameters while still achieving reliable bonds without excessive intermetallic growth.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Ni—Mg alloy ensures robust bonding between aluminum and non-aluminum metals, improving the durability of clad materials and composite materials used in electronic components and structural components without degrading bonding strength at elevated temperatures.

Implementation Method 1

maintaining bonding strength by reducing aluminum oxide at the interface

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 2

bonding an aluminum layer to a copper layer excellent in heat conductivity to each other through an iron layer or a nickel layer by means of pressure welding and diffusion bonding

Methodology Applied
Scientific EffectDiffusion bonding: Diffusion Welding

Implementation Method 3

bonding an aluminum layer to a copper layer excellent in heat conductivity to each other through an iron layer or a nickel layer by means of pressure welding and diffusion bonding

Methodology Applied
Scientific EffectPressure welding: Welding

Implementation Method 4

The aluminum cooler and the aluminum layer of the heat-diffusion facilitating layer are brazed together

Methodology Applied
Scientific EffectBrazing: Brazing

Data Source

PatentUS8883318B2Aluminum bonding alloy, and clad material and aluminum bonding composite material each having bonding alloy layer made of the alloy
Publication Date: 2014.11.11 NEOMAX MATERIALS
  • US8883318B2 patent drawing
  • US8883318B2 patent drawing
  • US8883318B2 patent drawing

AI summary

An aluminum bonding alloy is an Ni—Mg alloy for bonding aluminum and a non-aluminum metal selected from steel, copper, nickel or titanium. The Ni—Mg alloy consists essentially of 0.08-0.90 mass % Mg, and the balance of Ni and inevitable impurities. A clad material includes a non-aluminum metal layer made of the non-aluminum metal and a bonding alloy layer made of the aluminum bonding alloy. The non-aluminum metal layer and the bonding alloy layer are bonded together by pressure welding and diffusion bonding.