Joining Dissimilar Ni and Nb Alloys via Transition Layer

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Solution Overview

Problem

Ni-based alloys and Nb-based alloys are thermodynamically incompatible, making direct welding or additive manufacturing challenging, leading to spallation, cracks, and defects during fabrication of composite articles.

Innovation Solution

A composite article is formed by using a transition material with a different composition sandwiched between Ni-based and Nb-based alloys, creating a compositional gradient to join the two alloys, allowing for successful integration through additive manufacturing processes like Directed Energy Deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If direct welding or additive manufacturing is attempted between Ni-based alloys and Nb-based alloys, then the fabrication process is simplified, but spallation and cracks occur due to thermodynamic incompatibility

Engineering Contradiction:
Improvefabrication process simplicityVSAvoidjoint integrity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A transition material layer is introduced between the Ni-based alloy and Nb-based alloy to serve as an intermediary that is compatible with both materials. This transition layer prevents direct contact between the thermodynamically incompatible Ni and Nb alloys, thereby avoiding spallation and cracks while enabling successful fabrication through additive manufacturing processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The composition of the transition material varies through its thickness, creating a compositional gradient that changes from being more Ni-compatible at the Ni-alloy interface to more Nb-compatible at the Nb-alloy interface. This local variation in material properties allows each region of the transition layer to be optimized for compatibility with its adjacent material, resolving the thermodynamic incompatibility issue.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If functionally graded transitions are used from Ni-based alloy to Nb-based alloy, then direct joining is achieved, but localized cracks and non-equilibrium phases form during fabrication

Engineering Contradiction:
Improvedirect joining capabilityVSAvoiddefect-free fabrication
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The transition material acts as a mediator that enables direct joining of Ni-based and Nb-based alloys through additive manufacturing. By selecting a transition material with appropriate intermediate properties and compatibility with both alloys, the process achieves direct joining without the defects associated with conventional functionally graded transitions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The composition parameters of the transition material are specifically selected and controlled to prevent the formation of non-equilibrium phases and localized cracks during additive manufacturing. The transition material's composition is designed to remain within stable phase regions during the thermal cycling of the fabrication process, thereby achieving defect-free fabrication.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The transition material effectively joins dissimilar alloys, alleviating thermal mismatch, residual stress, and property transitions, enhancing the structural integrity and performance of composite articles.

Implementation Method 1

additive manufacturing processes like Directed Energy Deposition

Methodology Applied
Scientific EffectLaser heating: Laser

Data Source

PatentUS20240316636A1Method of joining two dissimilar alloys and composite articles including the same
Publication Date: 2024.09.26 UT BATTELLE LLC
  • US20240316636A1 patent drawing
  • US20240316636A1 patent drawing
  • US20240316636A1 patent drawing

AI summary

A composite article is provided. The composite article includes a first portion comprising a first alloy having a first composition, and a second portion comprising a second alloy having a second composition. The second composition is different than the first composition. A transition portion joins the first portion to the second portion, and comprises a transition material having a composition that is different than both the first composition of the first alloy and the second composition of the second alloy. The transition portion includes only the transition material or a compositional gradient. The first alloy may be a high-strength material, and the second alloy may be an extreme-temperature material, or vice versa. The transition material may be a Ti-based alloy, a refractory element, or a refractory alloy other than a Nb-based alloy. A method of fabricating the composite article and a method of joining two dissimilar alloys are also provided.