Nickel-Base Alloy Additive Manufacturing Crack Resistance

Solution Overview

Problem

Nickel-base alloys used in additive manufacturing, such as selective laser melting, suffer from microcrack formation during processing and limited mechanical properties, including creep resistance and oxidation resistance, which restricts their application in high-temperature components.

Innovation Solution

A nickel-base superalloy composition with specific weight percentages of elements like chromium, cobalt, titanium, aluminum, and tantalum, along with additives like yttrium oxide, is developed to enhance mechanical properties and reduce cracking, enabling crack-free production and improved oxidation resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If nickel-base materials are built up with layer thickness up to 40 μm, then productivity is improved, but mechanical properties such as creep resistance are insufficient

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent applies parameter changes by optimizing the chemical composition of the nickel-base alloy within specific ranges: chromium (20-25%), cobalt (15-20%), tungsten (1.5-2.5%), titanium (2.5-3.5%), aluminum (2.0-3.0%), boron (0.005-0.015%), and zirconium (0.002-0.008%). These compositional parameters are precisely controlled to achieve both crack-free additive manufacturing with 40 μm layer thickness and adequate creep resistance for high-temperature applications.

Inventive Principle:
Principle #35Parameter changes

2Strength

If alternative alloys are used to improve mechanical properties, then creep resistance is improved, but microcrack formation occurs during SLM process

Engineering Contradiction:
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent resolves this contradiction by precisely controlling alloy composition parameters, particularly chromium at 20-25% and cobalt at 15-20%, which enhance high-temperature strength and creep resistance. The controlled composition prevents microcrack formation during selective laser melting while maintaining adequate creep resistance, eliminating the trade-off between mechanical properties and manufacturing reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite alloy system combining nickel with multiple alloying elements (chromium, cobalt, tungsten, titanium, aluminum, boron, zirconium) in specific proportions. This multi-element composite composition synergistically improves both creep resistance and resistance to microcrack formation during additive manufacturing, achieving properties superior to single-element additions.

Inventive Principle:
Principle #40Composite materials

3Strength

If alternative alloys are used to improve mechanical properties, then strength is improved, but macrocrack formation occurs during heat treatment

Engineering Contradiction:
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent controls the composition parameters to prevent macrocrack formation during heat treatment. Specifically, the chromium content (20-25%) provides oxidation resistance and strengthens the matrix, while cobalt (15-20%) enhances high-temperature strength. The balanced composition prevents excessive hardening and stress concentration that would lead to macrocracks during heat treatment, maintaining both mechanical properties and reliability.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If layer thickness is reduced to 20 μm to improve build quality, then manufacturing precision is improved, but productivity is reduced

Engineering Contradiction:
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent enables the use of 40 μm layer thickness (double the conventional 20 μm) by optimizing the alloy composition with specific ranges of chromium, cobalt, tungsten, titanium, aluminum, boron, and zirconium. This compositional parameter optimization ensures adequate mechanical properties and crack-free building at the increased layer thickness, thereby doubling productivity while maintaining acceptable build quality for many applications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alloy achieves improved mechanical properties and increased oxidation resistance, reducing the likelihood of cracking during heat treatment and enhancing the productivity of additive manufacturing processes like selective laser melting.

Implementation Method 1

additive manufacturing by means of selective energy irradiation, such as laser radiation

Methodology Applied
Scientific EffectSelective laser melting: Laser

Implementation Method 2

oxidation resistance is often limited... increased oxidation resistance

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Data Source

PatentUS11753701B2Nickel-based alloy for additive manufacturing and method
Publication Date: 2023.09.12

AI summary

An alloy is provided by the targeted selection of some elements of silicone, manganese, sulfur, chromium, titanium, aluminum, zirconium, tantalum, iron, copper, niobium, yttrium and yttrium oxide, which can be readily processed and also provides good mechanical characteristic values for the produced component.