Nickel-Coated Battery Electrode Substrate for Strength and Flexibility

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Solution Overview

Problem

Existing battery electrode substrates for alkaline secondary batteries face issues with strength, flexibility, high electrical resistance, and reduced cycle life due to inadequate metal coverage and adhesiveness, leading to increased costs and impaired charge/discharge characteristics.

Innovation Solution

A battery electrode substrate with a metallic porous body featuring a nickel film coating of at least 85% coverage on plastic fibers, a core/sheath composite fiber structure, and a specific pore size range, combined with a gradient nickel film density and electroplating methods to enhance strength, flexibility, and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the amount of Ni metal is increased to secure strength, then the collector strength is improved, but the flexibility is lost and metal fiber protrusion causes short circuiting

Engineering Contradiction:
Improvecollector strengthVSAvoidflexibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent uses a composite structure combining metal fibers (for strength and conductivity) with polymer unwoven fabric (for flexibility and structural support). This composite approach allows the collector to achieve both high strength and flexibility simultaneously, preventing metal fiber protrusion while maintaining bendability for electrode formation.

Inventive Principle:
Principle #40Composite materials

2Strength

If the amount of Ni metal is increased to secure strength, then the collector strength is improved, but the cost is driven up

Engineering Contradiction:
Improvecollector strengthVSAvoidcost
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

By combining metal fibers with polymer unwoven fabric, the patent reduces the overall amount of expensive Ni metal required while maintaining structural strength. The polymer fabric provides mechanical support, allowing less metal to be used without compromising collector integrity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies metal plating selectively to specific regions where conductivity and strength are most needed, rather than uniformly coating the entire collector. This localized approach reduces total metal consumption while maintaining performance in critical areas.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If the amount of Ni plating is reduced to lower cost, then the cost is reduced, but the electrical resistance increases and output characteristics are impaired

Engineering Contradiction:
ImprovecostVSAvoidelectrical resistance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The composite structure of metal fibers embedded in polymer fabric provides inherent electrical conductivity through the metal network, reducing dependence on thick Ni plating layers. This allows cost reduction through minimized plating while maintaining low electrical resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies Ni plating selectively to regions requiring enhanced conductivity and current collection, rather than uniform coverage. This localized plating strategy reduces total Ni consumption and cost while maintaining adequate electrical performance in critical zones.

Inventive Principle:
Principle #3Local quality

4Quantity of substance

If the metal film coverage on fiber surface is reduced to lower cost, then the cost is reduced, but the current flow is impaired and electrical resistance increases

Engineering Contradiction:
ImprovecostVSAvoidcurrent flow
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent implements selective Ni plating on metal fiber surfaces, applying coating only in regions where current collection is critical. This partial coverage approach reduces Ni consumption and cost while maintaining sufficient conductivity for effective current flow in active zones.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The metal fiber-polymer composite structure provides continuous electrical pathways through the metal network, reducing dependence on complete fiber surface coating. This allows reduced plating coverage while maintaining adequate current flow capability.

Inventive Principle:
Principle #40Composite materials

5Shape

If the unwoven fabric is bent by winding, then the battery structure is formed, but the metal layer exfoliates and electrical resistance increases

Engineering Contradiction:
Improvebattery structureVSAvoidelectrical resistance
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The composite of metal fibers and polymer unwoven fabric creates a flexible, integrated structure where the polymer matrix holds metal fibers together during winding. This prevents metal layer exfoliation during battery assembly while enabling the necessary bent configuration for electrode formation.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a substrate with improved strength, flexibility, and reduced electrical resistance, enabling high-rate charge/discharge capabilities and extended cycle life while minimizing nickel usage and costs.

Implementation Method 1

a metallic porous body, the metallic porous body having a structure in which a surface of a plastic fiber in a woven or unwoven fabric is coated with a nickel film

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 2

a conductive layer is formed on a polymer core material such as unwoven fabric by a vapor-phase method such as sputtering

Methodology Applied
Scientific EffectVapor-phase deposition: Physical Vapour Deposition

Implementation Method 3

a conductive layer is formed on a polymer core material such as unwoven fabric by a vapor-phase method such as sputtering

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS7998621B2Collector, battery electrode substrate, and methods for producing the same
Publication Date: 2011.08.16 SUMITOMO ELECTRIC INDUSTRIES LTD
  • US7998621B2 patent drawing
  • US7998621B2 patent drawing
  • US7998621B2 patent drawing

AI summary

A battery electrode substrate includes a metallic porous body. The metallic porous body has a structure in which a surface of a plastic fiber in a woven or unwoven fabric is coated with a nickel film. The nickel film coats the surface with an average coverage ratio of not less than 85%.