Nickel-Core Braze Coating Structure for Binder-Free Oxidation Control

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Solution Overview

Problem

Existing braze coating materials with a nickel core and coating suffer from residual organic binder issues, oxidation tendencies, and poor processability, leading to quality inconsistencies and increased costs.

Innovation Solution

A braze coating material with a nickel core, a coating layer containing hard particles and brazing flux, a hardened layer with a second brazing flux, and a protective silicate layer, eliminating the need for an organic binder and preventing oxidation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If nickel-based brazing filler material is used as the low melting point component, then the brazed coating has high hardness and wear resistance, but the material is hard, brittle, and poor in processability, making it difficult to process into wire-shaped or strip-shaped forms

Engineering Contradiction:
ImprovehardnessVSAvoidprocessability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The nickel-based brazing filler material is segmented into two functional parts: a nickel core providing mechanical strength and processability, and a coating layer containing the brazing filler material powder providing hardness and wear resistance. This segmentation allows each part to fulfill its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite structure combining a nickel core with a coating layer containing hard particles, binder, and brazing filler material. This composite material approach integrates the ductility and processability of nickel with the hardness and wear resistance of the brazing filler material, resolving the contradiction between strength and manufacturability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If powdered brazing filler material is used with organic binder, then the material can be processed and applied, but the organic binder residue during use affects the quality of the braze coating

Engineering Contradiction:
ImproveprocessabilityVSAvoidquality
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The harmful organic binder is extracted and replaced with an inorganic binder system. The coating layer uses a water-based slurry containing inorganic binder materials that do not produce harmful residues during brazing, eliminating the quality issue while maintaining processability through the slurry application method.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of manufacture

If powdery metal particles are exposed outside the coating, then the brazing filler material can be applied, but the particles are easily oxidized and deteriorated during transportation and storage

Engineering Contradiction:
ImproveapplicabilityVSAvoidoxidation resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A protective coating layer is formed around the nickel core, creating a protective shell that prevents oxidation of the metal particles during transportation and storage. This thin film structure maintains the applicability of the brazing material while providing the necessary protection against environmental degradation.

Inventive Principle:
Principle #30Flexible shells and thin films

4Reliability

If brazing flux is continuously added during braze coating procedure, then oxidation is prevented and wetting is facilitated, but work efficiency is reduced and cost increases

Engineering Contradiction:
Improveoxidation protectionVSAvoidwork efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The brazing flux is incorporated into the coating layer during the manufacturing process, before the actual brazing operation. This preliminary incorporation eliminates the need for continuous addition of flux during the brazing procedure, improving work efficiency while maintaining oxidation protection and wetting properties.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a stable, oxidation-resistant braze coating with strong adhesion, reduced moisture absorption, and improved welding quality, facilitating automated production and reducing residual carbon content.

Implementation Method 1

The nickel core is metallic nickel having a roughened surface

Methodology Applied
Scientific EffectMechanical interlocking:

Implementation Method 2

it is necessary to continuously add a brazing flux during the braze coating procedure, which results in low work efficiency and easily causes a large waste of the brazing flux and higher cost

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Implementation Method 3

to facilitate wetting and spreading of the brazing filler material on the surfaces of the hard alloy/diamond particles and the base material

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 4

The braze coating method involves making a brazed coating metallurgically bonded with the base material, wherein the bonding strength is much higher than the mechanical bonding in the thermal spraying

Methodology Applied
Scientific EffectMetallurgical bonding: Diffusion Welding

Implementation Method 5

the brazed coating has a smooth surface and high construction accuracy, and can reach the required accuracy by being less processed

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS12420361B2Braze coating material with nickel core and coating and preparation method and braze coating method thereof
Publication Date: 2025.09.23 ZHENGZHOU RES INST OF MECHANICAL ENG CO LTD
  • US12420361B2 patent drawing

AI summary

A braze coating material with a nickel core and a coating, a preparation method thereof, and a braze coating method are provided. The braze coating material with a nickel core and a coating requires no binder and has strong adhesion ability, and includes the nickel core, a coating layer, a hardened layer, and a protective layer sequentially from inside to outside. The nickel core is metallic nickel having a surface subjected to a roughening treatment. The coating layer is a first brazing flux layer including hard particles, a first brazing flux, and a brazing filler metal powder. The hardened layer contains a second brazing flux and is covered with the protective layer mainly composed of a silicate.