Nickel Interlayer Brazing of TiAl Alloy

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Solution Overview

Problem

Intermetallic TiAl alloys are fragile and cannot be screwed, bolted, or riveted, and existing brazing methods face challenges due to incompatibility and low melting point eutectic alloy formation with nickel, cobalt, and iron-based alloys, limiting their use in high-temperature applications.

Innovation Solution

A layer of nickel is interposed between the TiAl alloy and a brazing alloy, with the assembly being heated in a vacuum to create a diffusion bond, forming a stable composite structure with specific phases that enhances mechanical strength and resistance to thermal and mechanical stresses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If brazing is used to join TiAl alloy with nickel-based alloys, then joining capability is achieved, but low melting point eutectic alloys form causing joint failure

Engineering Contradiction:
Improvejoining strengthVSAvoidjoint stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

A nickel interlayer is introduced between the TiAl alloy and the nickel-based alloy to be joined. This interlayer prevents direct contact between TiAl and the nickel-based alloy, thereby avoiding the formation of low melting point eutectic alloys that would compromise joint reliability. The nickel interlayer acts as a mediator that enables successful brazing while maintaining joint stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If diffusion brazing is used to avoid low melting point eutectics, then joint reliability improves, but process complexity increases

Engineering Contradiction:
Improvejoint stabilityVSAvoidbrazing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The nickel interlayer is pre-applied to the TiAl alloy surface before the brazing process. This preliminary action prepares the surface in advance to prevent eutectic formation during brazing, simplifying the overall process by eliminating the need for complex diffusion brazing procedures while still achieving reliable joints.

Inventive Principle:
Principle #10Preliminary action

3Weight of moving object

If TiAl alloy is used for aeronautic components, then mass reduction is achieved, but cold fragility prevents mechanical joining

Engineering Contradiction:
Improvecomponent massVSAvoidmechanical joining capability
Core Design Contradiction:
Weight of moving objectVSEase of manufacture

Solution Approach 1:

Mechanical joining methods (screwing, bolting, riveting) are replaced with brazing technology. The nickel interlayer enables successful brazing of TiAl alloy by preventing eutectic formation, thereby substituting mechanical joining with a thermal joining process that is suitable for cold-fragile intermetallic materials while maintaining the weight advantages of TiAl.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves a strong, crack-free bond between TiAl and nickel-based alloys, allowing for high-temperature operation without cracking, and the nickel layer acts as a buffer to absorb mechanical stresses, improving the durability and usability of the composite parts.

Implementation Method 1

a layer of nickel is interposed between the first part and the brazing alloy

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

the assembly to be processed is raised to a temperature higher than the melting point of the brazing alloy for at least ten minutes in a vacuum

Methodology Applied
Scientific EffectVacuum heating: Heating

Implementation Method 3

by melting a brazing alloy adapted to the second material

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS7749614B2Method of brazing a Ti-Al alloy
Publication Date: 2010.07.06 OFFICE NAT DETUDES & DE RECH AEROSPATIALES
  • US7749614B2 patent drawing
  • US7749614B2 patent drawing

AI summary

The invention relates to a method of brazing a Ti—Al alloy. According to the invention, a layer of nickel (2) is disposed between a part (1) which is made from titanium aluminide and a brazing sheet (3), such as to enable: the aforementioned part (1) to be brazed to another metallic material (4) without the aluminium diffusing from one to the other; and a stable link with good mechanical strength to be produced. The invention can be used for the assembly of aircraft engine parts which are made from titanium aluminide and nickel-based superalloy.