Nickel Silicide Interconnects for Ultra-Fine Semiconductor Devices

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current semiconductor manufacturing techniques face challenges in forming interconnect patterns with line widths of 10 nanometers or less, as materials like copper and tungsten suffer from increased wire resistance due to electron scattering and poor adhesion, making it difficult to achieve stable and low-resistance interconnects.

Innovation Solution

The method involves forming amorphous silicon coatings on support elements, followed by siliciding to create nickel silicide interconnects, which reduces resistance and enhances adhesion, allowing for the formation of stable, low-resistance interconnects with line widths as small as 5 nanometers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If copper or tungsten is used for interconnect patterns with line widths of 10 nanometers or less, then the interconnect can be formed, but wire resistance increases due to electron scattering and adhesion problems occur

Engineering Contradiction:
Improveinterconnect line widthVSAvoidwire resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the material parameter from conventional metals (copper, tungsten) to nickel silicide, and changes the formation method parameter from metal RIE to siliciding process. This parameter change resolves the contradiction by achieving low resistance (comparable to or lower than copper) and excellent adhesion while maintaining ultra-fine line widths of 10 nm or less

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite approach by forming nickel silicide through the reaction of nickel metal with silicon. This composite material (nickel silicide) combines the low resistance properties of metals with the adhesion benefits of silicon, resolving the contradiction between low wire resistance and good adhesion at ultra-fine dimensions

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If copper or tungsten is used for interconnect patterns, then the interconnect can be formed, but adhesion problems occur

Engineering Contradiction:
Improveinterconnect line widthVSAvoidadhesion
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent introduces silicon as an intermediary material that reacts with nickel to form nickel silicide. This intermediary approach resolves the adhesion problem by creating a material that inherently bonds well to silicon-based semiconductor structures, eliminating the adhesion issues experienced with conventional metals like copper and tungsten

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the material parameter from pure metals (copper, tungsten) to a metal silicide compound (nickel silicide). This parameter change resolves the adhesion contradiction by providing excellent adhesion to silicon substrates and interlayer insulating films while maintaining ultra-fine line width capability

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If miniaturized patterns are formed to increase capacity, then higher capacity is achieved, but resistance increases due to electron scattering

Engineering Contradiction:
Improvedevice capacityVSAvoidwire resistance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent changes the material parameter to nickel silicide, which has superior electrical properties at ultra-fine dimensions. This parameter change resolves the contradiction by maintaining low resistance even when line widths are reduced to 10 nm or less, enabling higher device capacity without the resistance penalty that would normally accompany miniaturization

Inventive Principle:
Principle #35Parameter changes

4Reliability

If nickel silicide is formed through siliciding process, then resistance is reduced and adhesion is enhanced, but additional process steps are required

Engineering Contradiction:
Improvewire resistanceVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the interconnect formation process with the siliciding process. By depositing nickel metal and then performing a siliciding heat treatment, the process combines material deposition with chemical reaction to directly form the low-resistance nickel silicide interconnect. This merging approach resolves the contradiction by achieving superior electrical properties without adding excessive process complexity

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent performs preliminary nickel metal deposition before the siliciding reaction. This preliminary action prepares the structure for the subsequent heat treatment that will transform the nickel into low-resistance nickel silicide. The preliminary deposition step enables the final siliciding process to produce the desired low-resistance interconnect with good adhesion

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of interconnects with significantly reduced resistance and improved stability, even at miniaturized sizes, by avoiding metal RIE processes and utilizing nickel silicide's strong immunity to resistance increases, thus facilitating high-density, ultra-fine semiconductor devices.

Implementation Method 1

forming a coating of amorphous silicon on the side face of the first support element

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

siliciding the amorphous silicon of the coating to form an interconnect

Methodology Applied
Scientific EffectSiliciding: Chemical Bonding

Data Source

PatentUS9093504B2Semiconductor device manufacturing method and semiconductor device
Publication Date: 2015.07.28 KIOXIA CORP
  • US9093504B2 patent drawing
  • US9093504B2 patent drawing
  • US9093504B2 patent drawing

AI summary

A semiconductor device is manufactured by forming, on an insulating base material, a first support element having a side face that extends from a surface of the insulating base material, forming a coating of amorphous silicon on the side face of the first support element, filling an aperture disposed between the first support element and a second support element that extends from a surface of the insulating base material with an insulating film, planarizing the insulating film to expose an exposed portion of the coating and a surface of the first support element, and siliciding the amorphous silicon of the coating to form an interconnect.