Nickel Substrate Thin Film Capacitor Impurity Control

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Solution Overview

Problem

Thin film capacitors exhibit low capacity and high leak current when manufacturing conditions, such as increased annealing temperature or time, are altered, which affects the dielectric constant and insulation resistance.

Innovation Solution

A thin film capacitor is manufactured using a nickel substrate with a purity of 99.99% or above, where impurities like iron, titanium, and copper are diffused in controlled amounts to the dielectric layer during annealing, maintaining high capacity and low leak current, and the capacitor is designed with a dielectric layer thickness of 0.05 μm to 5 μm to prevent short circuits and stress-related cracks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of stationary object

If annealing temperature is raised or annealing time is extended to increase the dielectric constant, then the relative dielectric constant is improved, but the leak current increases and capacity decreases

Engineering Contradiction:
Improverelative dielectric constantVSAvoidleak current
Core Design Contradiction:
Area of stationary objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the nickel substrate by strictly controlling impurity content (Fe, Ti, Cu, Al, Mg, Mn, Si, Cr each at 65 ppm or below). This parameter change in substrate purity prevents excessive impurity diffusion during annealing, allowing the dielectric constant to be enhanced while maintaining low leak current and high capacity.

Inventive Principle:
Principle #35Parameter changes

2Area of stationary object

If annealing temperature is raised or annealing time is extended to increase the dielectric constant, then the relative dielectric constant is improved, but the capacity decreases

Engineering Contradiction:
Improverelative dielectric constantVSAvoidcapacity
Core Design Contradiction:
Area of stationary objectVSQuantity of substance

Solution Approach 1:

The patent changes the chemical composition parameters of the nickel substrate by strictly controlling impurity content (Fe, Ti, Cu, Al, Mg, Mn, Si, Cr each at 65 ppm or below). This parameter change in substrate purity prevents excessive impurity diffusion during annealing, allowing the dielectric constant to be enhanced while maintaining high capacity.

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If high temperature annealing is performed to enhance the relative dielectric constant, then the dielectric constant is improved, but impurity diffusion increases affecting dielectric layer properties

Engineering Contradiction:
Improverelative dielectric constantVSAvoidimpurity diffusion control
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The patent performs preliminary action by strictly controlling the impurity content in the nickel substrate before the annealing process. By pre-establishing low impurity levels (each impurity at 65 ppm or below), the substrate is prepared in advance to minimize impurity diffusion during subsequent high-temperature annealing, thereby maintaining manufacturing precision.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical composition parameters of the nickel substrate by strictly controlling impurity content (Fe, Ti, Cu, Al, Mg, Mn, Si, Cr each at 65 ppm or below). This parameter change in substrate purity prevents excessive impurity diffusion during annealing, allowing the dielectric constant to be enhanced while maintaining low leak current and high capacity.

Inventive Principle:
Principle #35Parameter changes

4Length of moving object

If the dielectric layer thickness is reduced to achieve thin-shaped capacitor, then the thin film shape is improved, but the risk of short circuit and crack formation increases

Engineering Contradiction:
Improvedielectric layer thicknessVSAvoidshort circuit prevention
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The patent changes the purity parameter of the nickel substrate to 99.99% or higher, which fundamentally alters the diffusion behavior during annealing. This parameter change ensures that even with thin dielectric layer thickness (0.05-5 μm), the low impurity content prevents degradation that would lead to short circuits or cracks, thereby maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

5Length of moving object

If the dielectric layer thickness is reduced to achieve thin-shaped capacitor, then the thin film shape is improved, but the risk of crack formation due to stress increases

Engineering Contradiction:
Improvedielectric layer thicknessVSAvoidcrack resistance
Core Design Contradiction:
Length of moving objectVSStrength

Solution Approach 1:

The patent changes the purity parameter of the nickel substrate to 99.99% or higher, which fundamentally alters the diffusion behavior during annealing. This parameter change ensures that even with thin dielectric layer thickness (0.05-5 μm), the low impurity content prevents degradation that would lead to short circuits or cracks, thereby maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a thin film capacitor with high capacity and low leak current, maintaining the dielectric layer's properties and preventing capacity reduction and crack formation, allowing for effective EMI control in LSI applications.

Implementation Method 1

the precursor dielectric layer is annealed to produce the thin film capacitor

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

the precursor dielectric layer is annealed so that the precursor dielectric layer is crystallized to be the dielectric layer

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 3

when one or more impurities (for example, at least one selected from the group consisting of iron, titanium, copper, aluminum, magnesium, manganese, silicon and chromium) included in the nickel substrate are diffused from the nickel substrate to the precursor dielectric layer during annealing

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS7561406B2Nickel substrate thin film capacitor and method of manufacturing nickel substrate thin film capacitor
Publication Date: 2009.07.14 TDK CORP
  • US7561406B2 patent drawing
  • US7561406B2 patent drawing
  • US7561406B2 patent drawing

AI summary

A thin film capacitor with high capacity and low leak current is provided. The thin film capacitor includes a nickel substrate with nickel (Ni) purity of 99.99 weight percent or above, and a dielectric layer and an electrode layer disposed in this order on the nickel substrate. The thin film capacitor is typically manufactured as follows. A precursor dielectric layer is formed on a nickel substrate with nickel purity of 99.99 weight percent or above, and is subjected to annealing to form a dielectric layer. The diffusion of impurities from the nickel substrate to the precursor dielectric layer during annealing is suppressed.