NiCr Surface Heating Element With Controlled Oxide for High-Temperature Use

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Solution Overview

Problem

Existing surface type heating elements for electric ranges face challenges such as material elution at high temperatures, low fracture toughness, high thermal expansion coefficients, and inadequate adhesion to substrates, leading to reliability and lifetime issues, and require lengthy high-temperature manufacturing processes that limit substrate material options and increase energy consumption.

Innovation Solution

A surface type heating element composed of a NiCr alloy with controlled oxygen content (1-3 wt%) and photonic sintering, which enhances fracture toughness, reduces thermal expansion, and ensures stable electrical resistivity and adhesive strength, eliminating the need for a reducing atmosphere and long-term high-temperature thermal treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If metal components with low melting point are used in heating elements, then ease of manufacture is improved, but operating temperature is limited to about 400°C and material elution occurs

Engineering Contradiction:
Improveease of manufactureVSAvoidoperating temperature
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The heating element uses a composite structure combining a metal powder layer (Ni, Cu, or their alloys) with a ceramic layer (alumina, zirconia, or magnesia). The metal layer provides electrical conductivity and ease of manufacturing, while the ceramic layer enables high-temperature operation (900°C or higher) and prevents material elution. This composite approach resolves the contradiction between ease of manufacture and high-temperature capability.

Inventive Principle:
Principle #40Composite materials

2Strength

If metal components are oxidized during thermal firing, then adhesive strength to substrate is improved, but electrical resistivity increases and output decreases

Engineering Contradiction:
Improveadhesive strengthVSAvoidelectrical output
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent controls the oxidation state of the metal powder layer by adjusting firing atmosphere parameters (oxidizing, neutral, or reducing atmosphere) and firing temperature (800-1000°C). By precisely controlling these parameters, the metal layer achieves optimal adhesive strength to the ceramic layer while maintaining electrical resistivity within the range of 10^-6 to 10^-4 Ω·cm, thus resolving the contradiction between adhesive strength and electrical output.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If thermal firing is used to manufacture heating elements with high melting point components, then high temperature resistance is improved, but manufacturing time increases and substrate material options are limited

Engineering Contradiction:
Improveheat resistanceVSAvoidmanufacturing time
Core Design Contradiction:
TemperatureVSLoss of time

Solution Approach 1:

The patent replaces traditional long-duration thermal firing with a optimized firing process that uses controlled atmosphere (oxidizing, neutral, or reducing) and specific temperature ranges (800-1000°C). This substitution reduces manufacturing time while achieving the same heat resistance效果, and the flexible atmosphere control allows various substrate materials to be used, resolving both the time consumption and substrate limitation issues.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Reliability

If metal powder layer is applied to substrate, then electrical conductivity is improved, but adhesion to ceramic layer or substrate is insufficient

Engineering Contradiction:
Improveelectrical conductivityVSAvoidadhesive strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent controls the oxidation state of the metal powder layer by adjusting firing parameters (atmosphere and temperature). This creates an optimal interface between the metal layer and ceramic layer/substrate, achieving both good electrical conductivity and strong adhesion. The controlled oxidation forms a metallurgical bond that satisfies both requirements simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The NiCr alloy surface type heating element operates effectively at high temperatures (400°C or more) with improved reliability and lifetime, reduced thermal shock, and stable electrical output, while simplifying the manufacturing process and reducing energy consumption.

Implementation Method 1

A surface type heating element composed of a NiCr alloy with controlled oxygen content (1-3 wt%) and photonic sintering

Methodology Applied
Scientific EffectPhotonic sintering: Selective Laser Sintering

Implementation Method 2

a surface type heating element which generates heat using electricity

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 3

controlled oxide layer... ensures stable electrical resistivity

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11832358B2Surface type heating element having controlled oxide layer and manufacturing method thereof
Publication Date: 2023.11.28 LG ELECTRONICS INC
  • US11832358B2 patent drawing
  • US11832358B2 patent drawing
  • US11832358B2 patent drawing

AI summary

Discussed are a surface type heating element which generates heat using electricity and a method of manufacturing the surface type heating element. The surface type heating element includes a NiCr alloy and has an oxygen content of 1 to 4 wt %, so that it can be used even at a high operating temperature of 400° C. or more, suppresses the elution of the material itself, has high fracture toughness, a low coefficient of thermal expansion, and heat resistance, and furthermore, ensures conductivity by having improved adhesive strength with respect to at least one of a substrate and an insulating layer, and controlled electrical resistivity.