Nitrate-Nitrogen Soil Measurement via 200 nm Absorption Spectroscopy

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Solution Overview

Problem

Conventional methods for measuring nitrate-nitrogen concentrations in soil are slow, expensive, and lack accuracy, hindering efficient agricultural practices and environmental sustainability due to reliance on laboratory-based testing and other techniques with calibration issues or interference factors.

Innovation Solution

A device measuring the attenuation spectrum of a soil-extractant mixture across a wavelength range including the 200 nm absorption peak, using a light source, detector, and processor to estimate nitrate-nitrogen concentration, accounting for interferences through physical models or empirical methods like partial least squares regression.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If laboratory-based soil measurement methods are used, then measurement accuracy is improved, but measurement time and cost increase significantly

Engineering Contradiction:
Improvenitrate-nitrogen concentration measurement accuracyVSAvoidtime from sampling to results
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent replaces the mechanical/chemical laboratory analysis system with an optical measurement system. A portable spectrophotometer measures light absorption by soil extracts in the field, eliminating the need for laboratory processing while maintaining measurement accuracy through spectral analysis of nitrate-nitrogen compounds.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces an extractant solution as an intermediary medium. The extractant chemically binds with nitrate-nitrogen in the soil, creating a measurable complex that can be analyzed optically. This intermediary enables field-based measurement while preserving the accuracy of laboratory methods.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If laboratory-based soil measurement methods are used, then measurement accuracy is improved, but measurement cost increases

Engineering Contradiction:
Improvenitrate-nitrogen concentration measurement accuracyVSAvoidcost per measurement
Core Design Contradiction:
Measurement precisionVSQuantity of substance

Solution Approach 1:

The patent replaces expensive laboratory instrumentation and processing with a portable, field-deployable spectrophotometer. This substitution dramatically reduces per-measurement costs while maintaining accuracy, enabling high-density sampling grids that were previously economically infeasible.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent enables farmers to perform their own soil testing without external laboratory services. The portable device allows on-farm measurement, eliminating mailing, handling, and laboratory processing costs, thereby reducing the overall cost per measurement.

Inventive Principle:
Principle #25Self-service

3Productivity

If ion-selective electrodes are used for fast measurement, then measurement speed is improved, but device reliability and ease of operation worsen

Engineering Contradiction:
Improvemeasurement speedVSAvoidmeasurement consistency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent replaces fragile ion-selective electrodes with a robust optical spectrophotometry system. Light-based measurement avoids the fragility and calibration issues of electrochemical sensors, providing consistent, reliable results without compromising measurement speed.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If NDVI-based canopy sensors are used, then measurement cost and speed are improved, but measurement accuracy and applicability worsen

Engineering Contradiction:
Improvemeasurement efficiencyVSAvoidnitrogen need inference accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent extracts the measurement target from the canopy level to the soil level. Instead of inferring nitrogen needs from plant color (NDVI), the system directly measures nitrate-nitrogen concentration in soil extracts, eliminating interference from water stress, disease, and other factors affecting plant appearance.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses soil extract as an intermediary that isolates nitrate-nitrogen measurement from confounding factors. The extractant solution selectively binds with nitrate-nitrogen, creating a clean optical signal that is not affected by canopy conditions, thereby improving accuracy while maintaining field-based efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid, accurate, and cost-effective measurement of nitrate-nitrogen levels in soil, allowing for real-time fertilizer management decisions and improving agricultural efficiency and environmental impact.

Implementation Method 1

Measurement of nitrate-nitrogen concentration in soil based on absorption spectroscopy

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Implementation Method 2

measuring the attenuation spectrum of a soil-extractant mixture across a wavelength range including the 200 nm absorption peak

Methodology Applied
Scientific EffectAbsorption of electromagnetic radiation: Absorption (EM radiation)

Data Source

PatentUS10488331B2Measurement of nitrate-nitrogen concentration in soil based on absorption spectroscopy
Publication Date: 2019.11.26 WINFIELD SOLUTIONS LLC
  • US10488331B2 patent drawing
  • US10488331B2 patent drawing
  • US10488331B2 patent drawing

AI summary

The nitrate-nitrogen concentration in soil is estimated based on the nitrate-nitrogen 200 nm absorption peak. In one embodiment, a device measures the attenuation spectrum of a soil-extractor mixture over a wavelength range that includes wavelengths in the vicinity of the 200 nm absorption peak (the spectral operating range) and then determines the nitrate-nitrogen concentration based on the attenuation spectrum.