Nitride Interconnects for Stable Memory Cell Density

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Solution Overview

Problem

Memory devices using variable resistance elements face challenges in achieving stable operations due to limitations in the size reduction of rectifying elements, which affects the density and stability of memory cells.

Innovation Solution

A memory device structure is developed with a first interconnect containing a nitride region and a first oxide layer, combined with a second oxide layer, allowing for a thin rectifying portion that enhances the density and stability of memory cells by utilizing a nitride of a specific metallic element, such as tungsten, and a hafnium oxide layer, facilitating efficient resistance switching and reducing leakage current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the size of rectifying elements is reduced to increase memory cell density, then memory cell density is improved, but operational stability deteriorates

Engineering Contradiction:
Improvememory cell densityVSAvoidoperational stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent employs a composite interconnect structure consisting of a first interconnect (tungsten nitride) and a second interconnect (molybdenum nitride) with different material compositions. This composite approach allows the rectifying portion to maintain stable electrical characteristics even when miniaturized, as the combination of different materials compensates for the size reduction effects, thereby improving operational stability while preserving high memory cell density

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters of the rectifying portion including the thickness ratio between the first and second interconnects (1:0.5 to 1:2), the nitrogen content in tungsten nitride (5-20 at%), and the thickness of each layer (5-50 nm range). By precisely controlling these parameters, the rectifying portion achieves stable operational characteristics at reduced dimensions, resolving the contradiction between miniaturization and stability

Inventive Principle:
Principle #35Parameter changes

2Reliability

If noble metals are used to achieve good rectifying characteristics, then rectifying performance is improved, but manufacturing cost increases

Engineering Contradiction:
Improverectifying characteristicVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive noble metals (such as platinum or gold traditionally used for rectifying contacts) with transition metal nitrides (tungsten nitride and molybdenum nitride). These alternative materials are significantly cheaper and can be deposited using standard sputtering techniques already present in semiconductor manufacturing lines, thereby improving ease of manufacture while maintaining good rectifying characteristics through proper compositional control

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent achieves noble metal-level rectifying performance by precisely controlling the nitrogen content (5-20 at% in tungsten nitride, 10-30 at% in molybdenum nitride) and layer thickness ratios. This parameter optimization enables the transition metal nitride composite to exhibit rectifying characteristics comparable to noble metals, eliminating the need for expensive materials while maintaining reliable performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed structure enables stable operations and increased memory cell density by maintaining a good rectifying characteristic and suppressing leakage current, while allowing for efficient programming, reading, and erasing operations without the need for expensive noble metals.

Implementation Method 1

A memory device structure is developed with a first interconnect containing a nitride region and a first oxide layer, combined with a second oxide layer, allowing for a thin rectifying portion that enhances the density and stability of memory cells by utilizing a nitride of a specific metallic element, such as tungsten, and a hafnium oxide layer, facilitating efficient resistance switching and reducing leakage current.

Methodology Applied
Scientific EffectResistive switching: Electrical Resistance

Data Source

PatentUS10256401B2Memory device with multiple interconnect lines
Publication Date: 2019.04.09 KIOXIA CORP
  • US10256401B2 patent drawing
  • US10256401B2 patent drawing
  • US10256401B2 patent drawing

AI summary

According to one embodiment, a memory device includes a first interconnect, a second interconnect, a first layer, a second layer. The first interconnect includes a first region and a second region. The first region extends in a first direction and includes a first metallic element. The second region extends in the first direction and includes the first metallic element and nitrogen. The second interconnect extends in a second direction crossing the first direction. A portion of the second region is positioned between the second interconnect and a portion of the first region. The first layer is provided between the second interconnect and the portion of the second region. The second layer is provided between the first layer and the second interconnect. The second layer includes at least one of silicon or a second oxide. The silicon is monocrystalline, polycrystalline, or amorphous.