Group-III Nitride Semiconductor Intermediate Layer for Crystallinity

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Solution Overview

Problem

Existing methods for manufacturing group-III nitride compound semiconductor light-emitting devices face challenges in achieving high crystallinity and productivity due to large lattice mismatches between substrates and nitride semiconductor crystals, leading to difficulties in forming uniform and high-quality films.

Innovation Solution

A method involving the formation of an intermediate layer using a sputtering technique that activates raw materials in plasma, with a thickness of 20 to 80 nm, to create a hexagonal close-packed structure as an alignment film on the substrate, allowing for the growth of high-crystallinity semiconductor layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a group-III nitride semiconductor crystal is epitaxially grown directly on a substrate, then the manufacturing process is simple, but the crystallinity is low due to large lattice mismatch

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidcrystallinity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

An intermediate layer made of a group-III nitride compound is introduced between the substrate and the semiconductor crystal. This intermediate layer serves as a mediator that reduces the lattice mismatch effect, enabling high-quality crystal growth. The intermediate layer has a hexagonal close-packed structure that provides a suitable template for epitaxial growth, thereby improving crystallinity without significantly complicating the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If a buffer layer is formed using MOCVD method, then the crystallinity is improved, but the manufacturing cost and process complexity increase

Engineering Contradiction:
ImprovecrystallinityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the formation method parameters from MOCVD to plasma processing (such as sputtering or plasma CVD). This parameter change allows the intermediate layer to be formed with a hexagonal close-packed structure that effectively reduces lattice mismatch. The plasma-based method achieves comparable or better crystallinity improvement while potentially reducing process complexity and cost compared to MOCVD.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If the thickness of the intermediate layer is increased, then the crystallinity is improved, but the manufacturing time and material consumption increase

Engineering Contradiction:
ImprovecrystallinityVSAvoidmanufacturing efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The invention optimizes the thickness parameter of the intermediate layer to a specific range (20-80 nm) where the hexagonal close-packed structure provides sufficient template effect for high-quality crystal growth. This optimized thickness achieves the necessary crystallinity improvement while minimizing manufacturing time and material consumption, thereby maintaining high productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of group-III nitride compound semiconductor light-emitting devices with improved crystallinity and productivity, achieving efficient emission characteristics while being cost-effective.

Implementation Method 1

A method involving the formation of an intermediate layer using a sputtering technique that activates raw materials in plasma

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 2

activates raw materials in plasma

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS9040319B2Group-III nitride compound semiconductor light-emitting device, method of manufacturing group-III nitride compound semiconductor light-emitting device, and lamp
Publication Date: 2015.05.26 TOYODA GOSEI CO LTD
  • US9040319B2 patent drawing
  • US9040319B2 patent drawing
  • US9040319B2 patent drawing

AI summary

A group-III nitride compound semiconductor light-emitting device, a method of manufacturing the group-III nitride compound semiconductor light-emitting device, and a lamp. The method includes the steps of: forming an intermediate layer (12) made of a group-III nitride compound on a substrate (11) by activating and reacting gas including a group-V element with a metal material in plasma; and sequentially forming an n-type semiconductor layer (14), a light-emitting layer (15), and a p-type semiconductor layer (16) each made of a group-III nitride compound semiconductor on the intermediate layer (12). Nitrogen is used as the group-V element, and the thickness of the intermediate layer (12) is in the range of 20 to 80 nm.