Nitride Semiconductor Protrusions for Light Extraction

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Solution Overview

Problem

Nitride semiconductor light-emitting devices face challenges in light extraction efficiency due to total reflection of photons within the device and increased dislocation density caused by lattice constant differences between substrates and semiconductor layers, leading to complex manufacturing processes and increased costs.

Innovation Solution

A method involving a combination of dry-etching and wet-etching processes to form protrusions on the substrate surface for growing nitride semiconductor materials, which improves light extraction efficiency and reduces dislocation density by using a sapphire substrate and additional semiconductor layers, allowing for better light emission and internal quantum efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a stacking-structure wall with a predetermined angle is formed to extract transverse light, then light extraction efficiency is improved, but manufacturing process complexity increases and manufacturing cost increases

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidmanufacturing process complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent forms protrusions with curved surfaces on the substrate instead of using flat stacking-structure walls. The protrusions have a hemispherical or dome-shaped top surface that gradually curves downward to the substrate, which simplifies the manufacturing process while still achieving effective light extraction through the curved interface between the protrusion and the surrounding medium.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent changes the geometric parameters of the substrate structure by forming protrusions with specific height, diameter, and curvature radius ratios. By optimizing these parameters, the patent achieves effective light extraction without requiring complex stacking structures, thereby simplifying the manufacturing process while maintaining improved light extraction efficiency.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If dry-etching alone is used to form protrusions, then manufacturing process is simpler, but byproducts remain on the substrate surface reducing semiconductor layer quality

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidsemiconductor layer quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent combines dry-etching and wet-etching processes in sequence. The dry-etching process first forms the protrusion structure, and then the wet-etching process removes the byproducts from the substrate surface. This combination of two processes achieves both the structural formation and the surface cleaning, thereby improving semiconductor layer quality without significantly complicating the manufacturing process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent implements a continuous manufacturing process where dry-etching and wet-etching are performed in immediate succession without intermediate steps. The wet-etching process continuously removes byproducts generated during dry-etching, ensuring that the substrate surface is always clean and ready for subsequent semiconductor layer deposition, thereby maintaining high manufacturing precision throughout the process.

Inventive Principle:
Principle #20Continuity of useful action

3Ease of manufacture

If a flat substrate surface is used, then manufacturing process is simpler, but dislocation density increases due to lattice constant difference between substrate and semiconductor layer

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoiddislocation density
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies local quality by creating protrusions with specific geometric characteristics on the substrate surface. The protrusions have different heights, diameters, and curvature radii that are locally optimized to reduce dislocation density in the overlying semiconductor layers. This local structural modification allows the bulk of the substrate to remain simple while the protrusion regions provide dislocation reduction benefits.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances light extraction efficiency by 40% and internal quantum efficiency by 10%, simplifying the manufacturing process and reducing costs by effectively removing byproducts and improving semiconductor layer quality.

Implementation Method 1

wet-etching the dry-etched substrate through the use of etching solution

Methodology Applied
Scientific EffectWet etching:

Implementation Method 2

forming protrusions on the substrate by dry-etching the substrate with the mask pattern through the use of etching gas

Methodology Applied
Scientific EffectDry etching:

Implementation Method 3

forming a first semiconductor layer on the substrate including the protrusions

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS8298842B2Method for manufacturing semiconductor light-emitting device
Publication Date: 2012.10.30 LG DISPLAY CO LTD
  • US8298842B2 patent drawing
  • US8298842B2 patent drawing
  • US8298842B2 patent drawing

AI summary

Disclosed is a method for manufacturing a semiconductor light-emitting device, which carries out a wet-etching process after a dry-etching process so as to form protrusions in a surface of a substrate for growing a nitride semiconductor material thereon. The method comprises coating a substrate with photoresist; forming a mask pattern on the substrate by selectively removing the photoresist; forming protrusions on the substrate by dry-etching the substrate with the mask pattern through the use of etching gas; wet-etching the dry-etched substrate through the use of etching solution; forming a first semiconductor layer on the substrate including the protrusions; forming an active layer on the first semiconductor layer; forming a second semiconductor layer on the active layer; etching predetermined portions of the active layer and second semiconductor layer until the first semiconductor layer is exposed; and forming a first electrode on a predetermined portion of the first semiconductor layer, wherein the active layer and second semiconductor layer are not formed on the predetermined portion of the first semiconductor layer, and forming a second electrode on the second semiconductor layer.