Nitride Semiconductor Surface Roughness via Selective Etching

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

In methods of manufacturing semiconductor devices, regrown nitride semiconductor layers often have a rough surface, which can lead to increased contact resistance and reduced device performance.

Innovation Solution

A method involving the formation of a first nitride semiconductor layer, followed by a first and second layer, with an opening exposing the first layer, and then forming a second nitride semiconductor layer of a specific conductivity type. The second layer is removed using an acidic solution, where the etching rate of the first layer is lower than the second layer, resulting in improved surface roughness and reduced contact resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a nitride semiconductor layer is regrown to reduce contact resistance, then contact resistance decreases, but surface roughness increases

Engineering Contradiction:
Improvecontact resistanceVSAvoidsurface roughness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent divides the protective layer into two distinct layers: a first layer (e.g., silicon nitride) with low etching rate and a second layer (e.g., zinc oxide) with high etching rate. This segmentation allows each layer to serve a specific function - the first layer protects the nitride semiconductor layer during etching, while the second layer is easily removed to reveal a smooth surface, thereby resolving the contradiction between contact resistance reduction and surface roughness control

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different materials with different etching rates to different layers, creating local quality variations. The first layer has low etching rate to protect the underlying nitride semiconductor layer, while the second layer has high etching rate for easy removal. This local differentiation of material properties enables simultaneous achievement of low contact resistance and smooth surface finish

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If a protective layer is formed during etching, then etching selectivity is improved, but process complexity increases

Engineering Contradiction:
Improveetching selectivityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes in etching rate between different materials to achieve selective removal. The second layer (zinc oxide) has a significantly higher etching rate than the first layer (silicon nitride), allowing the second layer to be removed while leaving the first layer intact. This parameter-based differentiation simplifies the process by using inherent material properties rather than complex process controls

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The first layer acts as an intermediary protective layer between the nitride semiconductor layer and the etching environment. It provides the necessary protection during etching operations while being designed to remain after the second layer is removed, thus mediating between the need for protection and the need for surface smoothness

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a semiconductor device with reduced surface roughness and lower contact resistance between the electrode and the nitride semiconductor layer, enhancing the performance of semiconductor devices like high-electron-mobility transistors.

Implementation Method 1

removing the second layer using an acidic solution; A first etching rate of the first layer for the acidic solution is lower than a second etching rate of the second layer for the acidic solution

Methodology Applied
Scientific EffectChemical etching:

Data Source

PatentUS20230036388A1Method of manufacturing semiconductor device
Publication Date: 2023.02.02 SUMITOMO ELECTRIC INDUSTRIES LTD
  • US20230036388A1 patent drawing
  • US20230036388A1 patent drawing
  • US20230036388A1 patent drawing

AI summary

A method of manufacturing a semiconductor device includes forming a first nitride semiconductor layer containing Ga on a substrate; forming a first layer on the first nitride semiconductor layer; forming a second layer on the first layer; forming an opening in which the first nitride semiconductor layer is exposed in the second layer and the first layer; forming a second nitride semiconductor layer of a first conductivity type on a surface, exposed in the opening, of the first nitride semiconductor layer; removing the second layer using an acidic solution; and after removing the second layer, forming an electrode on the second nitride semiconductor layer. A first etching rate of the first layer for the acidic solution is lower than a second etching rate of the second layer for the acidic solution.