Nitride Crystal Substrate Heating Accuracy via Free Carrier Absorption

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Solution Overview

Problem

Existing methods for heating nitride crystal substrates in semiconductor manufacturing lack accuracy and reproducibility, particularly in setting heating conditions based on the absorption coefficient, leading to variations in crystallinity and device performance.

Innovation Solution

A nitride crystal substrate with a specific absorption coefficient expression (α=nKλa) in the 1 μm to 3.3 μm wavelength range, allowing for precise control of heating through free carrier absorption, ensuring high accuracy and reproducibility in heating processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional heating methods are used for nitride crystal substrates, then heating can be performed, but heating accuracy and reproducibility are insufficient

Engineering Contradiction:
Improveheating accuracyVSAvoidheating reproducibility
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the free electron concentration (n) in the nitride crystal substrate to achieve a specific absorption coefficient range. By adjusting the doping concentration of n-type impurities to 1×10^18 to 1×10^19 atoms/cm³, the absorption coefficient at 2 μm wavelength is controlled to 1.2 to 48 cm⁻¹, enabling accurate and reproducible heating when irradiated with infrared light.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If the absorption coefficient is not precisely controlled, then manufacturing is easier, but heating accuracy deteriorates

Engineering Contradiction:
Improveheating accuracyVSAvoidsubstrate manufacturing complexity
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent specifies precise parameter ranges for free electron concentration (1×10^18 to 1×10^19 atoms/cm³) and absorption coefficient (1.2 to 48 cm⁻¹ at 2 μm wavelength) to achieve accurate heating. These parameter controls enable reproducible heating performance while maintaining manufacturability through defined doping concentration ranges.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables stable and uniform heating of the substrate, improving crystallinity and reducing crystal strain, which in turn enhances the quality and consistency of semiconductor devices by accurately controlling temperature and impurity concentrations.

Implementation Method 1

an absorption coefficient α is approximately expressed by equation (1) in a wavelength range of at least 1 μm or more and 3.3 μm or less: α=nKλa (wherein, λ(μm) is a wavelength, α(cm−1) is absorption coefficient of the nitride crystal substrate at 27° C., n (cm−3) is a free electron concentration in the nitride crystal substrate)

Methodology Applied
Scientific EffectFree carrier absorption: Absorption (EM radiation)

Data Source

PatentUS11339500B2Nitride crystal substrate, semiconductor laminate, method of manufacturing semiconductor laminate and method of manufacturing semiconductor device
Publication Date: 2022.05.24 SUMITOMO CHEM CO LTD
  • US11339500B2 patent drawing
  • US11339500B2 patent drawing
  • US11339500B2 patent drawing

AI summary

There is provided a nitride crystal substrate comprising group-III nitride crystal and containing n-type impurities, wherein an absorption coefficient α is approximately expressed by equation (1) in a wavelength range of at least 1 μm or more and 3.3 μm or less: α=n Kλa (1) (wherein, λ(μm) is a wavelength, α(cm−1) is absorption coefficient of the nitride crystal substrate at 27° C., n (cm−3) is a free electron concentration in the nitride crystal substrate, and K and a are constants, satisfying 1.5×10−19≤K≤6.0×10−19, a=3).