Nitrogen-Containing Dielectric Polymers for Low-Energy Actuation

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Solution Overview

Problem

There is a need for electroactive materials that exhibit a large mechanical response to a relatively small energy input, which is essential for energy-efficient applications such as robotics, pumps, and prosthetic devices, as existing materials often require higher electrical energy inputs to achieve significant mechanical deformation.

Innovation Solution

The development of electroactive polymer devices featuring at least one layer of a dielectric polymer formed from ethylenically unsaturated nitrogen-containing monomers, excluding acrylonitrile, which are used in piezoelectric, pyroelectric, actuator, or sensor applications, allowing for mechanical displacement upon the application of an electric field.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional electroactive materials are used, then mechanical deformation can be achieved, but high electrical energy input is required

Engineering Contradiction:
Improveelectrical energy inputVSAvoidmechanical response
Core Design Contradiction:
Use of energy by moving objectVSForce

Solution Approach 1:

The patent changes the chemical composition parameters of the dielectric polymer by selecting specific ethylenically unsaturated nitrogen-containing monomers (such as N-vinylpyrrolidone, N-vinylcaprolactam, N-vinylimidazole) with particular molecular structures and dipole moments. This chemical parameter change results in enhanced electroactive properties, allowing the material to achieve greater mechanical deformation at lower electrical energy inputs compared to conventional electroactive materials.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If conventional dielectric polymers are used, then device simplicity is maintained, but pre-straining is required to achieve adequate displacement

Engineering Contradiction:
Improvepre-straining requirementVSAvoiddisplacement
Core Design Contradiction:
Ease of operationVSShape

Solution Approach 1:

The patent modifies the physical-chemical parameters of the dielectric polymer layer by selecting monomers with specific glass transition temperatures, molecular weights, and chain flexibilities. These parameter changes result in a polymer that achieves adequate displacement without requiring pre-straining, as the intrinsic molecular structure provides sufficient electroactive response under normal operating conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These polymer devices demonstrate high modulus of elasticity and significant displacement relative to the applied electric field, offering improved energy conversion efficiency and reduced need for pre-straining, making them suitable for various applications including robotics and medical devices.

Implementation Method 1

Upon application of an electric field across the actuating component, the at least one layer of the dielectric polymer is mechanically displaced

Methodology Applied
Scientific EffectElectrostatic actuation: Electrostatics

Data Source

PatentEP2379608B1Electroactive polymers and articles containing them
Publication Date: 2019.12.25 3M INNOVATIVE PROPERTIES CO
  • EP2379608B1 patent drawingFigure 1
  • EP2379608B1 patent drawing
  • EP2379608B1 patent drawing

AI summary

An electroactive polymer device is described that includes at least one layer of a dielectric polymer that is a polymerized product of at least one ethylenically unsaturated nitrogen-containing monomer. Also disclosed is a transducer that includes the electroactive polymer as disclosed.