Nitrogen-Containing Host Material for OLED Emission Layer Efficiency

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in reducing driving voltage and increasing emission efficiency and lifetime, necessitating the development of suitable materials for improved performance.

Innovation Solution

A light emitting device incorporating a nitrogen-containing compound, specifically a compound represented by Formula 1, is used in the emission layer, which includes a first compound with a carbazole group and a second carbazole group connected through a nitrogen atom, and a phenyl or triphenyl silane moiety as a substituent, acting as a host to enhance emission efficiency and device life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional materials are used in the emission layer, then the device can operate, but the emission efficiency and device lifetime are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the molecular structure of the host material by introducing specific substituents (carbazole groups, phenyl silane moieties) to change the triplet energy level parameter. This structural parameter change enables more efficient energy transfer to dopants and reduces efficiency degradation over time, simultaneously improving emission efficiency and device lifetime.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite molecular structure combining carbazole groups with phenyl or triphenyl silane moieties. This composite structure leverages the high triplet energy of carbazole and the stability of silane groups to achieve both high emission efficiency and improved device lifetime through synergistic effects.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If the triplet energy difference between host and dopant is small, then energy transfer is efficient, but efficiency degradation occurs rapidly

Engineering Contradiction:
Improveenergy transfer efficiencyVSAvoidemission efficiency stability
Core Design Contradiction:
Use of energy by moving objectVSDuration of action of stationary object

Solution Approach 1:

The patent optimizes the triplet energy parameter of the host material to achieve an ideal balance: the carbazole-based host provides sufficiently high triplet energy (2.5-3.5 eV) to enable efficient energy transfer to common dopants, while the specific substituent design prevents excessive energy transfer that causes rapid efficiency degradation.

Inventive Principle:
Principle #35Parameter changes

3Power

If driving voltage is reduced, then power consumption decreases, but emission efficiency and lifetime are compromised

Engineering Contradiction:
Improvedriving voltageVSAvoidemission efficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The modified host material with carbazole and phenyl silane groups improves charge transport properties and exciton management, enabling efficient electroluminescence at lower driving voltages. The enhanced triplet energy and improved molecular packing facilitate better charge injection and reduced voltage requirements while maintaining high emission efficiency.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nitrogen-containing compound reduces energy transfer with dopants, suppresses efficiency degradation, and improves color purity and device life by increasing the triplet energy difference, resulting in high emission efficiency and extended device lifespan.

Implementation Method 1

The organic electroluminescence display is different from a liquid crystal display and is a display of a self-luminescent type or kind in which holes and electrons injected from a first electrode and a second electrode recombine in an emission layer so that a light emitting material in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240147851A1Light emitting device and nitrogen-containing compound for light emitting device
Publication Date: 2024.05.02 SAMSUNG DISPLAY CO LTD
  • US20240147851A1 patent drawing
  • US20240147851A1 patent drawing
  • US20240147851A1 patent drawing

AI summary

A light emitting device of one or more embodiments includes a first electrode, a second electrode oppositely provided to the first electrode, and an emission layer provided between the first electrode and the second electrode, wherein the emission layer includes a first compound represented by Formula 1 below.