Nitrogen-Containing Hole Transport Material for OLED Efficiency

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Solution Overview

Problem

Current organic electroluminescence display devices face challenges in achieving low driving voltage, high luminous efficiency, and long service life, particularly in the development of materials for the hole transport layer.

Innovation Solution

Incorporating nitrogen-containing compounds, specifically those with a carbazole substituent linked to a benzofuroindole or benzothienoindole skeleton, in the hole transport region and emission layer to enhance hole transport ability and reduce electron resistance, thereby improving the efficiency and lifespan of light-emitting devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in the hole transport layer, then the device structure is simple, but the luminous efficiency and service life are insufficient

Engineering Contradiction:
Improveservice lifeVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining carbazole substituents with benzofuroindole or benzothienoindole skeletons to create a novel nitrogen-containing compound. This composite molecular structure integrates the hole-transporting capability of carbazole with the structural stability and electron resistance reduction properties of the benzofuroindole/benzothienoindole core, thereby simultaneously improving luminous efficiency and service life while maintaining reasonable device complexity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies molecular parameters by introducing specific nitrogen-containing functional groups and adjusting the molecular structure of the hole transport material. These parameter changes in the material's chemical structure lead to improved charge transport properties, higher luminous efficiency, and extended device lifespan without significantly complicating the overall device architecture

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional hole transport materials are used, then the manufacturing process is simple, but the hole transport ability and electron resistance reduction are insufficient

Engineering Contradiction:
Improvehole transport abilityVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent achieves enhanced hole transport ability by changing the molecular parameters of the hole transport material through introducing nitrogen-containing functional groups. The modified molecular structure improves charge carrier mobility and reduces electron resistance, thereby increasing productivity in terms of charge transport efficiency while the synthesis remains feasible through standard organic chemistry methods

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If materials for low driving voltage are used, then the driving voltage is reduced, but the luminous efficiency and service life may be compromised

Engineering Contradiction:
Improvedriving voltageVSAvoidluminous efficiency
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent uses composite materials with nitrogen-containing compounds that simultaneously enable low driving voltage operation and maintain high luminous efficiency. The unique molecular structure facilitates efficient charge injection and transport at lower voltages while the carbazole-benzofuroindole/benzothienoindole composite structure ensures high radiative efficiency and device stability, resolving the trade-off between voltage reduction and performance maintenance

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS20220310934A1Compound including nitrogen emitting device including the same
Publication Date: 2022.09.29 SAMSUNG DISPLAY CO LTD
  • US20220310934A1 patent drawing
  • US20220310934A1 patent drawing
  • US20220310934A1 patent drawing

AI summary

A light emitting device includes: a first electrode; a second electrode facing the first electrode; and a plurality of organic layers disposed between the first electrode and the second electrode, wherein at least one of the organic layers includes a compound including a nitrogen moiety, and the compound is of Formula 1 below:wherein, in Formula 1, the variables are defined herein.