Nitrogen-Modified Tungsten Silicide for E-Fuse Resistance Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current semiconductor devices face challenges in forming efficient e-fuse and precision resistor structures that minimize power consumption and maximize speed, particularly in achieving low resistance and temperature coefficient of resistance (TCR) for one-time-programmable memory elements like E-fuses.

Innovation Solution

A method involving the deposition of a tungsten silicon layer with a specific silicon-to-tungsten ratio, followed by nitrogen introduction through low-temperature nitridation to form a nitrogen-containing tungsten silicon layer, which reduces resistance and TCR, and is used to create an electrical connection between conductive materials, enabling efficient e-fuse and resistor structures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional conducting material stripes are used for E-fuse structures, then the basic memory function is achieved, but the resistance and temperature coefficient of resistance (TCR) are not sufficiently low for high-performance applications

Engineering Contradiction:
Improveresistance stabilityVSAvoidresistance control precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by modifying the composition parameters of the conducting material. Specifically, it uses tungsten silicide (WxSi100-x) where the tungsten content x is controlled within 5-50 atomic percent, and introduces nitrogen content controlled at 1-40 atomic percent. These compositional parameter changes enable precise control of resistance and TCR values to achieve the desired electrical characteristics for high-performance E-fuse structures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating a multi-component system consisting of tungsten, silicon, and nitrogen. The tungsten silicide base material is further modified through nitrogen incorporation, forming a composite structure that combines the beneficial properties of each element: tungsten provides low resistivity, silicon enables compositional tuning, and nitrogen reduces TCR. This composite approach allows simultaneous optimization of multiple electrical parameters

Inventive Principle:
Principle #40Composite materials

2Speed

If high current pulses are used for electromigration programming, then programming speed is improved, but the material must withstand high stress without excessive resistance increase

Engineering Contradiction:
Improveprogramming speedVSAvoidmaterial stability under stress
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent addresses material stability under high stress by optimizing the crystal structure and compositional distribution. The controlled formation of tungsten silicide with specific stoichiometry and nitrogen incorporation creates a more uniform and stable microstructure that can withstand the mechanical and electrical stress of high current pulses during electromigration programming, preventing excessive resistance increase while maintaining programming speed

Inventive Principle:
Principle #14Spheroidality (Curvature)

3Reliability

If nitrogen is introduced into tungsten silicon layer, then resistance and TCR are reduced, but additional processing steps are required

Engineering Contradiction:
Improveelectrical property stabilityVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges multiple functions into the nitrogen introduction step. The nitrogen incorporation process simultaneously achieves several objectives: it modifies the electrical properties to reduce resistance and TCR, stabilizes the material composition, and enhances the overall performance of the E-fuse structure. By combining these multiple benefits into a single processing step, the patent minimizes the increase in fabrication complexity while maximizing the improvement in electrical property stability

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in reduced resistance and TCR, enhancing the performance of semiconductor devices by improving the transport properties of the material, making them suitable for high-density current pulses and electromigration programming.

Implementation Method 1

Nitrogen may be introduced into the tungsten silicon layer to form a nitrogen-containing tungsten silicon layer

Methodology Applied
Scientific EffectNitridation: Nitriding

Data Source

PatentUS10192822B2Modified tungsten silicon
Publication Date: 2019.01.29 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10192822B2 patent drawing
  • US10192822B2 patent drawing
  • US10192822B2 patent drawing

AI summary

A method for forming a precision resistor or an e-fuse structure where tungsten silicon is used. The tungsten silicon layer is modified by implanting nitrogen into the structure.