Nitrogen-Containing Organic Compound for OLED Stability

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Solution Overview

Problem

Current organic light emitting diodes (OLEDs) face challenges in achieving high efficiency and long lifespan due to limitations in hole and electron mobility and electrochemical stability, particularly for large-size flat panel displays.

Innovation Solution

An organic compound with a specific chemical structure, represented by Chemical Formula 1, is introduced, which includes a ring with nitrogen that facilitates charge injection and balances hole and electron flows, improving the efficiency and stability of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic materials are used in OLEDs, then the device can be manufactured with current technology, but the hole and electron mobility remain limited and electrochemical stability is insufficient

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by changing chemical parameters - specifically introducing a pyrimidine ring structure with nitrogen atoms at positions 1 and 3, and substituting aromatic groups at positions 2 and 4. This structural parameter change enhances electrochemical stability and charge carrier mobility while maintaining manufacturability through established organic synthesis methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite organic materials by combining the pyrimidine core structure with various aromatic substituent groups (such as phenyl, naphthyl, carbazolyl groups). This composite approach allows optimization of both electrochemical stability and charge transport properties while using well-established synthetic chemistry techniques

Inventive Principle:
Principle #40Composite materials

2Productivity

If organic materials with higher hole and electron mobility are developed, then OLED efficiency improves, but electrochemical stability may be compromised

Engineering Contradiction:
ImproveOLED efficiencyVSAvoidelectrochemical stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by introducing nitrogen atoms at specific positions (1 and 3) within the pyrimidine ring structure, and placing electron-donating or electron-withdrawing aromatic groups at specific positions (2 and 4). This localized structural modification optimizes charge carrier mobility in the horizontal direction while maintaining electrochemical stability through the rigid pyrimidine core

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The pyrimidine ring structure acts as an intermediary between the electrode and the aromatic substituent groups. It provides a stable electrochemical platform while facilitating efficient charge transport to the emitting layers, thereby mediating between stability requirements and efficiency requirements

Inventive Principle:
Principle #24Intermediary (Mediator)

3Power

If the organic layer uses materials with improved charge transport, then driving voltage decreases and luminance increases, but the lifespan of the OLED may be reduced

Engineering Contradiction:
Improvedriving voltageVSAvoidOLED lifespan
Core Design Contradiction:
PowerVSDuration of action of stationary object

Solution Approach 1:

The patent employs beforehand cushioning by incorporating antioxidant and stabilizing aromatic groups (such as carbazolyl and triphenylamine groups) into the organic compound structure before device operation. These groups preemptively protect against degradation from high driving voltages and intense luminance, thereby extending OLED lifespan while maintaining low operating voltage

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound results in OLEDs with low driving voltage, high luminance, and extended lifespan, enhancing the performance and durability of organic optoelectric devices.

Implementation Method 1

a ring which includes at least one nitrogen and is combined with a substituted or unsubstituted fused ring in a 1:1 molar ratio, thereby interacting with a electrode to facilitate charge injection

Methodology Applied
Scientific EffectCharge injection: Conduction (electrical)

Data Source

PatentUS10680190B2Organic compound, organic optoelectronic element, and display device
Publication Date: 2020.06.09 SAMSUNG SDI CO LTD
  • US10680190B2 patent drawing
  • US10680190B2 patent drawing
  • US10680190B2 patent drawing

AI summary

The present invention relates to an organic compound by chemical formula 1, and an organic optoelectronic element and a display device each comprising the organic compound.