Nitrogen-Containing Phosphor for White LED Color Rendering

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Solution Overview

Problem

Current white LED illumination systems using high luminance blue LEDs and garnet-based yellow phosphors suffer from inferior color rendering properties due to insufficient red light emission and variations in emission intensity and peak wavelength, leading to inconsistent color tones.

Innovation Solution

Development of a new phosphor with a broad emission spectrum in the blue color range (400nm to 500nm) and a flat excitation band in the near ultraviolet/ultraviolet region, combined with a manufacturing method that minimizes composition shift within phosphor particles to enhance emission efficiency and luminance, using a specific composition formula MmAaBbOoNn:Z with controlled elemental ratios and atmospheric conditions during firing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If high luminance blue LED and garnet-based yellow phosphor are combined, then luminance is improved, but color rendering properties deteriorate due to insufficient red light emission

Engineering Contradiction:
ImproveluminanceVSAvoidcolor rendering properties
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent combines multiple phosphor materials (garnet-based yellow phosphor, phosphor with yellow to red emission peak, and phosphor containing nitrogen) to create a composite phosphor system. This composite approach allows the system to maintain high luminance from the blue LED and yellow phosphor while adding red light emission through the red-emitting phosphor components, thereby improving color rendering properties without sacrificing luminance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent divides the illumination system into multiple functional components: a high luminance blue LED source, a garnet-based yellow phosphor for converting blue to yellow light, and additional phosphors (including red-emitting phosphors and nitrogen-containing phosphors) for enhancing specific wavelength ranges. This segmentation allows each component to be optimized for its specific function while working together to achieve both high luminance and excellent color rendering.

Inventive Principle:
Principle #1Segmentation

2Illumination intensity

If garnet-based yellow phosphor is applied on LED, then blue and yellow light emission is achieved, but color tone consistency deteriorates due to variation in emission intensity and peak wavelength

Engineering Contradiction:
Improveblue and yellow light emissionVSAvoidcolor tone consistency
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent modifies the phosphor composition parameters by incorporating phosphors with broad emission spectra and flat excitation bands. The nitrogen-containing phosphor and red-emitting phosphor are selected to have emission characteristics that complement the garnet-based yellow phosphor, creating a more stable overall emission profile. This parameter optimization reduces sensitivity to variations in individual phosphor performance, thereby improving color tone consistency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a phosphor combination where the broad emission spectrum and flat excitation band characteristics provide inherent feedback stabilization. The nitrogen-containing phosphor and red-emitting phosphor act as buffer components that compensate for fluctuations in the garnet-based yellow phosphor's emission intensity and peak wavelength, maintaining consistent color output through the synergistic interaction of multiple phosphor materials.

Inventive Principle:
Principle #23Feedback

3Illumination intensity

If phosphor film thickness is increased, then emission intensity is improved, but transmitted blue light intensity changes causing color tone variation

Engineering Contradiction:
Improveemission intensityVSAvoidcolor tone stability
Core Design Contradiction:
Illumination intensityVSEase of operation

Solution Approach 1:

The patent uses a composite phosphor system where the nitrogen-containing phosphor and red-emitting phosphor are combined with the garnet-based yellow phosphor. This composite structure allows the system to achieve high emission intensity through increased phosphor content while the broad emission spectra and complementary wavelength ranges of the different phosphors work together to maintain stable color tone, reducing the negative impact of film thickness variations on blue light transmission.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new phosphor achieves significant improvements in emission intensity and luminance, providing high-efficient white LED illumination with excellent color rendering properties and consistent color tones by optimizing the distribution of atoms within the phosphor particles and using a specific composition formula.

Implementation Method 1

the phosphor having an excitation band in a wavelength region of near ultraviolet/ultraviolet to blue color generated from the LED

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentEP2067840B1Fluorescent substance, fluorescent sheets, process for production of the fluorescent substance, and light-emitting devices made by using the substance
Publication Date: 2018.08.15 NICHIA CORP
  • EP2067840B1 patent drawingFigure 1(A)~1(C)
  • EP2067840B1 patent drawingFigure 2(A)~2(E)
  • EP2067840B1 patent drawingFigure 3

AI summary

To provide a phosphor given by a general composition formula expressed by MmAaBbOoNn:Z, (wherein element M is one or more kinds of elements having bivalent valency, element A is one or more kinds of elements having tervalent valency, element B is one or more kinds of elements having tetravalent valency, O is oxygen, N is nitrogen, and element Z is one or more kinds of activating agent, satisfying m > 0, a > 0, b > 0, o ≥ 0, and n > 0), with a change rate of a ratio of element B atoms to the total numbers of atoms being smaller by 10% or the change rate of oxygen atoms to the total numbers of atoms being smaller by 40% in a range from a particle surface up to depth 2000nm, having a broad emission spectrum in a range of blue color, having a broad flat excitation band in a range of near ultraviolet/ultraviolet, and having excellent emission efficiency, emission intensity, and luminance.