Nitrogen Removal via Dynamic DO Control in Wastewater Reactors

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Solution Overview

Problem

Control of nitrite oxidizing bacteria (NOB) in low strength wastewater remains challenging, as existing methods are not effective in maintaining stable nitritation and require careful manipulation of temperature, free ammonia, and dissolved oxygen levels, which are not feasible across a wide range of temperatures.

Innovation Solution

A system and method that control aerobic-anoxic duration and dissolved oxygen concentration based on the ratio of ammonia to the sum of nitrite and nitrate concentrations in real time, favoring ammonia oxidizing bacteria (AOB) over NOB, thereby maximizing nitrogen removal through mechanisms like nitrification-denitrification and nitritation-denitritation in a single tank.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional nitrification-denitrification is used, then nitrogen removal is achieved, but oxygen consumption and organic carbon requirements increase significantly

Engineering Contradiction:
Improveaeration energyVSAvoidnitrogen removal efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent applies parameter changes by controlling dissolved oxygen concentration and aeration duration to maintain ammonia to nitrite+nitrate ratio near 1, enabling partial nitritation-denitritation that consumes less oxygen while achieving equivalent nitrogen removal. This dynamic parameter control resolves the contradiction between energy loss and productivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system uses periodic aeration cycles with controlled durations to create alternating aerobic and anoxic conditions in a single reactor. This periodic action enables both nitrification and denitrification to occur sequentially, reducing overall aeration energy requirements while maintaining nitrogen removal efficiency.

Inventive Principle:
Principle #19Periodic action

2Loss of energy

If nitrite oxidizing bacteria are repressed to achieve short-cut nitrogen removal, then oxygen and organic carbon consumption decrease, but control stability becomes difficult to maintain

Engineering Contradiction:
Improveaeration energyVSAvoidprocess stability
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent implements feedback control by continuously monitoring ammonia, nitrite, nitrate, and dissolved oxygen concentrations, then adjusting aeration duration and intensity to maintain the ammonia to nitrite+nitrate ratio near 1. This feedback mechanism ensures stable repression of NOB while maintaining process reliability.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts aeration parameters based on real-time microbial community status and substrate concentrations. By making the aeration regime dynamic rather than static, the system can adapt to maintain optimal conditions for AOB while suppressing NOB, resolving the contradiction between energy savings and process stability.

Inventive Principle:
Principle #15Dynamics

3Productivity

If separate tanks with mixed liquor recycling are used for nitrification and denitrification, then nitrogen removal is achieved, but system complexity and space requirements increase

Engineering Contradiction:
Improvenitrogen removal efficiencyVSAvoidreactor configuration
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges nitrification and denitrification functions into a single reactor by implementing periodic aeration cycles. This consolidation eliminates the need for separate tanks and mixed liquor recycling systems, reducing device complexity while maintaining nitrogen removal efficiency through temporal separation of aerobic and anoxic phases.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

By using periodic aeration to create alternating aerobic and anoxic zones within a single reactor, the system achieves both nitrification and denitrification without requiring physical separation into multiple tanks. This periodic action resolves the contradiction between productivity and device complexity.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach maximizes nitrogen removal by balancing ammonia oxidation and denitrification, reduces aeration and organic carbon requirements, and effectively represses NOB, achieving efficient nitrogen removal in low strength wastewater treatment.

Implementation Method 1

ammonia oxidation and denitrification balance each other while also favoring AOB over NOB

Methodology Applied
Scientific EffectNitrification: Oxidation

Implementation Method 2

denitrification (dependent on COD input) and subsequent ammonia oxidation balance each other

Methodology Applied
Scientific EffectDenitrification: Reduction

Data Source

PatentUS9469558B2Method and apparatus for maximizing nitrogen removal from wastewater
Publication Date: 2016.10.18 D C WATER & SEWER AUTHORITY
  • US9469558B2 patent drawing
  • US9469558B2 patent drawing
  • US9469558B2 patent drawing

AI summary

A reactor and control method thereof to maximize nitrogen removal and minimize aeration requirement through control of transient anoxia and aerobic SRT, repression of NOB, and control of dynamic DO concentrations or aeration interval by keeping the reactor NH4 and NOx concentrations approximately equal has been proposed. Controls described in this invention maximizes the potential for TIN removal through nitrification, limited nitritation, nitritation, denitrification, limited denitritation, denitritation making use of 1) real time measurement of ammonia, nitrite, nitrate, 2) operational DO and the proper use of DO setpoints, and 3) proper implementation of transient anoxia within a wide range of reactor configurations and operating conditions.