Diluent Nitrogen Saturation for IGCC Combustor Stability

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Solution Overview

Problem

In Integrated Gasification Combined Cycle (IGCC) plants, the addition of water vapor as a diluent in syngas leads to variations in heating value, affecting combustor performance and efficiency, and moisture lowers firing temperature, potentially outweighing benefits.

Innovation Solution

A method and apparatus that produce nitrogen process gas, saturate it with water vapor, and heat it using waste process heat and compressor extraction air to supply dry syngas to the combustor, maintaining a constant heating value and enhancing efficiency by using low-level process heat to pre-heat diluent nitrogen and steam turbine condensate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If water vapor is added as diluent to syngas to improve mass flow through combustor, then mass flow is improved, but heating value varies and firing temperature decreases

Engineering Contradiction:
Improvemass flow through combustorVSAvoidfiring temperature
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The patent changes the physical state of nitrogen from dry gas to saturated vapor state by controlling water vapor content, and adjusts temperature parameters through heating processes. This allows nitrogen to serve as diluent while maintaining stable heating value and firing temperature, resolving the contradiction between mass flow improvement and temperature maintenance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a saturator and heater system as intermediary equipment between nitrogen production and combustor. This intermediary system conditions the nitrogen by saturating it with water vapor and heating it to specific temperature ranges, enabling the nitrogen to function as an effective diluent that maintains both mass flow and firing temperature stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If water vapor is added as diluent to syngas, then mass flow is improved, but combustor efficiency decreases

Engineering Contradiction:
Improvemass flow through combustorVSAvoidcombustor efficiency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent optimizes water vapor content parameters in nitrogen to achieve saturation point, and controls temperature parameters through heating. These parameter changes enable nitrogen to maintain stable heating value while improving mass flow, thereby enhancing combustor efficiency rather than decreasing it.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes waste process heat from the IGCC plant to heat and saturate nitrogen, making the system self-sufficient. The waste heat that would otherwise be unused is now utilized to condition the diluent nitrogen, improving overall plant efficiency while maintaining combustor performance.

Inventive Principle:
Principle #25Self-service

3Quantity of substance

If nitrogen is saturated with water vapor to act as diluent, then diluent availability is improved, but heating value stability deteriorates

Engineering Contradiction:
Improvediluent availabilityVSAvoidheating value stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent precisely controls water vapor content parameters to achieve nitrogen saturation point, and adjusts temperature parameters through heating processes. These controlled parameter changes ensure that the saturated nitrogen maintains stable heating value while providing sufficient diluent quantity, resolving the contradiction between availability and stability.

Inventive Principle:
Principle #35Parameter changes

4Loss of energy

If waste process heat is used to heat saturated nitrogen, then plant efficiency is improved, but heat recovery requirements increase

Engineering Contradiction:
Improvewaste process heat utilizationVSAvoidheat recovery system complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent designs the heat recovery system to serve multiple functions: heating saturated nitrogen to combustion temperature, preheating feedwater, and generating steam. This multi-functionality approach maximizes waste heat utilization while avoiding excessive system complexity, as a single integrated heat recovery system handles multiple energy recovery tasks.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach maintains constant combustor firing temperature and efficiency, allows efficient burning of dry syngas, and increases IGCC plant efficiency by utilizing waste process heat effectively.

Implementation Method 1

saturating the NPG with the water vapor

Methodology Applied
Scientific EffectSaturation: Supersaturation

Implementation Method 2

the HRSG is configured to heat the low pressure steam loop

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

a heat exchanger configured to heat the NPG using waste process heat and extraction air from the compressor

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentUS8671694B2Methods and apparatus for diluent nitrogen saturation
Publication Date: 2014.03.18 AIR PROD & CHEM INC
  • US8671694B2 patent drawing
  • US8671694B2 patent drawing

AI summary

In one aspect, an embodiment of the present disclosure provides an Integrated Gasification Combined Cycle (IGCC) apparatus. The apparatus includes a saturator configured to saturate NPG with water vapor, and a heat recovery steam generator (HRSG), a low pressure steam loop through the saturator, wherein the HRSG is configured to heat the low pressure steam loop. The apparatus further includes a compressor and a heat exchanger configured to heat the NPG using waste process heat and extraction air from the compressor, wherein the heated NPG thereby becomes diluent nitrogen.