Nitrogen Microalloyed Spring Steel for Strength-Fatigue Balance

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Solution Overview

Problem

The spring industry in China faces challenges with low-grade ordinary springs and a shortage of high-end products, particularly in high-strength, high-stress, and special-shaped parts, due to performance gaps and unstable quality indicators, which fail to meet the demands of high-end equipment manufacturing, especially under high-speed and high-stress conditions.

Innovation Solution

A nitrogen-containing microalloyed spring steel with specific chemical compositions (C: 0.45-0.52%, Si: 0.15-0.35%, Mn: 0.90-1.10%, Cr: 0.90-1.15%, Mo: 0.10-0.25%, V: 0.10-0.20%, Nb: 0.025-0.04%, N: 0.007-0.012%, and controlled levels of other elements) is developed, along with a preparation method involving smelting, refining, vacuum degassing, continuous casting, and controlled cooling and quenching processes to enhance mechanical strength, elongation, and fatigue resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional spring steel compositions and processes are used, then production cost and manufacturing simplicity are maintained, but mechanical strength, fatigue resistance, and quality stability are insufficient for high-end applications

Engineering Contradiction:
Improvemechanical strengthVSAvoidcomposition complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition parameters of the spring steel, including carbon content (0.45-0.52%), silicon (0.15-0.35%), manganese (0.90-1.10%), chromium (0.90-1.15%), molybdenum (0.10-0.25%), vanadium (0.10-0.20%), and niobium (0.025-0.04%). This systematic parameter optimization enables the steel to achieve superior mechanical strength, fatigue resistance, and quality stability required for high-end applications while managing composition complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating a multi-element alloy system that combines carbon, silicon, manganese, chromium, molybdenum, vanadium, and niobium in specific proportions. This composite alloy structure synergistically enhances the mechanical properties and fatigue resistance of the spring steel, resolving the contradiction between strength improvement and composition complexity

Inventive Principle:
Principle #40Composite materials

2Strength

If carbon content is increased to improve strength, then elastic strength and hardness improve, but plasticity and toughness deteriorate

Engineering Contradiction:
Improveelastic strengthVSAvoidplasticity
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by optimizing the carbon content within a specific range (0.45-0.52%) rather than using excessive carbon. This controlled parameter adjustment, combined with additions of alloying elements like nickel and molybdenum, achieves the desired balance between elastic strength and plasticity, preventing the deterioration of ductile properties that would occur with higher carbon content alone

Inventive Principle:
Principle #35Parameter changes

3Reliability

If alloying elements are added to improve mechanical properties, then strength and fatigue resistance improve, but manufacturing cost increases

Engineering Contradiction:
Improvefatigue resistanceVSAvoidalloying element content
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent applies parameter changes by precisely controlling the content ranges of multiple alloying elements: silicon (0.15-0.35%), manganese (0.90-1.10%), chromium (0.90-1.15%), molybdenum (0.10-0.25%), vanadium (0.10-0.20%), and niobium (0.025-0.04%). This optimized parameter combination achieves high fatigue resistance and reliability while managing the quantity and cost of alloying elements through efficient distribution across multiple elements rather than excessive addition of single elements

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting spring steel exhibits improved hardness, tensile strength, yield strength, elongation, and fatigue cycles, with reduced decarburization and increased toughness, effectively addressing the performance gaps and enhancing the suitability for high-end applications.

Implementation Method 1

Through solid-solution strengthening, carbon improves the elastic strength, hardness and wear resistance of the spring steel

Methodology Applied
Scientific EffectSolid-solution strengthening: Solid Solution Strengthening

Implementation Method 2

Through solid-solution strengthening of ferrite, silicon improves the elasticity of the steel

Methodology Applied
Scientific EffectSolid-solution strengthening: Solid Solution Strengthening

Implementation Method 3

Mn can improve the strength of the steel through a solution treatment and simultaneously improve the hardenability of the steel

Methodology Applied
Scientific EffectSolution treatment:

Implementation Method 4

Through a solution treatment, chromium improves the strength, hardenability and tempering stability of the steel

Methodology Applied
Scientific EffectSolution treatment:

Implementation Method 5

Through a solution treatment, Mo improves the strength of the steel, greatly improves the hardenability of the steel

Methodology Applied
Scientific EffectSolution treatment:

Implementation Method 6

V and Nb form finely dispersed VC, NbC, VN, or NbN in the steel, which greatly strengthens the matrix, refines the grain boundaries, and stops the growth of grains

Methodology Applied
Scientific EffectPrecipitation hardening: Precipitation Hardening

Implementation Method 7

Nitrogen improves the elasticity, strength and hardness of the steel through a stronger solid solution strengthening

Methodology Applied
Scientific EffectSolid solution strengthening: Solid Solution Strengthening

Implementation Method 8

subjecting the steel ingot to peeling, re-heating continuous rolling, controlled cooling, quenching, and tempering to obtain a spring steel product

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS11466334B2Nitrogen-containing microalloyed spring steel and preparation method thereof
Publication Date: 2022.10.11 SHANDONG AUTOMOBILE SPRING FACTORY ZIBO CO LTD

AI summary

A nitrogen-containing microalloyed spring steel and a preparation method thereof are provided. The chemical components are: 0.45-0.52% of carbon, 0.15-0.35% of silicon, 0.90-1.10% of manganese, 0.90-1.15% of chromium, 0.10-0.25% of molybdenum, 0.10-0.20% of vanadium, 0.025-0.04% of niobium, 0.007-0.012% of nitrogen, less than or equal to 0.03% of lead, tin, zinc, antimony, and bismuth, less than or equal to 25 ppm of oxygen and hydrogen, less than or equal to 0.02% of sulfur and phosphorus, less than or equal to 0.2% of copper, less than or equal to 0.35% nickel, and a balance of iron. The spring steel has significantly improved properties, including high mechanical strength, large elongation, high reduction of area, and good anti-fatigue performance.