Downhole NMR Fluid Analyzer for Hydrocarbon Molecular Size Estimation

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Solution Overview

Problem

Hydrocarbon exploration is hindered by the difficulty in accurately characterizing subsurface hydrocarbons due to similar chemical characteristics, leading to ambiguous or false data when using conventional drilling instruments and tools.

Innovation Solution

A method and apparatus utilizing a downhole nuclear magnetic resonance (NMR) instrument to perform measurements in a static homogeneous magnetic field with RF pulses and pulsed magnetic field gradients, transforming signals into frequency and complex number domains to provide proton chemical-shift information and diffusion rates, enabling accurate estimation of hydrocarbon properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional drilling instruments are used to characterize hydrocarbons, then the measurement process is simple, but the measurement precision is poor due to similar chemical characteristics of different hydrocarbons leading to ambiguous or false data

Engineering Contradiction:
Improvehydrocarbon characterization accuracyVSAvoidmeasurement instrument complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by utilizing multiple NMR measurement parameters (chemical shift, diffusion coefficient, relaxation times) to characterize hydrocarbons. By measuring and analyzing multiple physical parameters simultaneously, the system can distinguish between different hydrocarbon types that have similar chemical characteristics, thereby improving measurement precision without requiring overly complex analytical chemistry methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses NMR as an intermediary measurement technique that indirectly characterizes hydrocarbons through their magnetic properties and molecular motion. Instead of directly analyzing chemical structure, the NMR instrument measures physical properties (chemical shift, diffusion, relaxation) that serve as intermediaries to infer hydrocarbon type and composition, improving accuracy while maintaining manageable device complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If multiple NMR measurements with different pulsed magnetic field gradients are performed, then the measurement precision for molecular size distribution is improved, but the measurement time and processing complexity increase

Engineering Contradiction:
Improvemolecular size distribution accuracyVSAvoidmeasurement and processing time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent employs periodic action by performing multiple NMR measurements with different pulsed magnetic field gradient magnitudes in a systematic sequence. Each measurement uses a specific gradient strength, and by periodically varying this parameter across multiple measurements, the system accumulates data needed to accurately determine molecular size distribution through diffusion coefficient analysis

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent applies preliminary action by first acquiring multiple NMR measurements with varying gradients before performing the complex data transformation and analysis. The raw data from these preliminary measurements are then processed through Fourier transformation and diffusion model fitting to extract molecular size information, separating the measurement phase from the computationally intensive analysis phase

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for precise characterization of hydrocarbon molecular composition and size, differentiating between similar hydrocarbon types and improving the accuracy of hydrocarbon identification in earth formations.

Implementation Method 1

performing a plurality of nuclear magnetic resonance (NMR) measurements on a sensitive volume in the sample using an NMR instrument where each measurement in the plurality of NMR measurements provides an electromagnetic waveform signal received with an antenna. Each NMR measurement in the plurality of NMR measurements is performed (a) in a static homogeneous magnetic field

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

with a sequence of pulses of radio-frequency (RF) electromagnetic energy transmitted from a transmitter antenna

Methodology Applied
Scientific EffectElectromagnetic radiation: Electromagnetic Induction

Implementation Method 3

with a series of pulsed magnetic field gradients being applied to the sample where the series is superimposed over the static homogeneous magnetic field and has a magnitude that is different from the magnitude in other NMR measurements

Methodology Applied
Scientific EffectMagnetic field gradient: Magnetic Field

Implementation Method 4

provides an electromagnetic waveform signal received with an antenna

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Data Source

PatentUS9645277B2Estimating molecular size distributions in formation fluid samples using a downhole NMR fluid analyzer
Publication Date: 2017.05.09 BAKER HUGHES CO
  • US9645277B2 patent drawing
  • US9645277B2 patent drawing
  • US9645277B2 patent drawing

AI summary

A method for estimating a property of subsurface material includes extracting a sample of the material using a downhole formation tester and performing a plurality of nuclear magnetic resonance (NMR) measurements on a sensitive volume in the sample where each measurement in the plurality is performed in a static homogeneous magnetic field with a pulsed magnetic field gradient that is different in magnitude from other NMR measurements to provide a waveform signal. The method further includes transforming each received waveform signal from a time domain into a frequency domain and comparing the frequency domain signal to a reference to provide proton chemical-shift information related to a chemical property of one or more molecules in the sample and transforming the frequency domain signals into a complex number domain that quantifies waveform signal amplitude changes to provide one or more diffusion rates with each diffusion rate being associated with a corresponding frequency.