Non-aqueous Liquid Anti-shrinkage Cement Additive

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional cement compositions in well cementing face challenges with shrinkage during hydration, leading to stress and potential failure of the cement sheath, which can result in micro-annuli, fluid migration, and compromised zonal isolation, necessitating costly repairs or well abandonment.

Innovation Solution

A non-aqueous liquid anti-shrinkage cement additive comprising a hydrocarbon liquid, dispersant, viscosifying additive, emulsifying agent, and calcined magnesium oxide is used to reduce or eliminate shrinkage, providing a swelling force that counteracts inward forces within the cement composition, thereby maintaining volume and enhancing mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cement composition is used, then the cement sheath provides structural support and fluid isolation, but the cement composition shrinks during hydration causing stress and potential failure

Engineering Contradiction:
Improvecement sheath integrityVSAvoidshrinkage-induced stress
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the physical and chemical parameters of the cement composition by incorporating specific additives (calcium aluminate cement, expanding clay, lime) that modify the hydration process. These parameter changes enable the cement to expand slightly during setting rather than shrink, counteracting the harmful shrinkage-induced stresses while maintaining structural integrity and reliability of the cement sheath.

Inventive Principle:
Principle #35Parameter changes

2Strength

If anti-shrink additive is added to enhance mechanical properties, then premature failure is prevented, but the additive composition complexity increases

Engineering Contradiction:
Improvemechanical properties of cement sheathVSAvoidadditive composition complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining multiple additives (calcium aluminate cement, expanding clay, lime) that work synergistically to enhance mechanical properties. This composite approach provides comprehensive performance improvement including strength, flexibility, and shrinkage compensation, while the additives are integrated into a unified cement composition formulation that manages complexity through proven compatibility and coordinated function.

Inventive Principle:
Principle #40Composite materials

3Productivity

If cement composition shrinks during hydration, then hydration process completes, but micro-annuli form and zonal isolation is compromised

Engineering Contradiction:
Improvehydration completionVSAvoidzonal isolation
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary anti-action by incorporating expanding additives (expanding clay, lime) that generate expansion forces during early hydration to counteract the subsequent shrinkage forces. This preliminary counter-measure prevents the formation of micro-annuli and maintains continuous zonal isolation throughout the hydration process and beyond, ensuring both complete hydration and reliable isolation.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The non-aqueous liquid anti-shrinkage cement additive effectively reduces shrinkage and enhances the mechanical properties of the cement sheath, preventing premature failure, maintaining zonal isolation, and reducing the risk of costly repairs or well abandonment.

Implementation Method 1

providing a swelling force that counteracts inward forces within the cement composition

Methodology Applied
Scientific EffectSwelling:

Implementation Method 2

effectively reduces shrinkage and enhances the mechanical properties of the cement sheath

Methodology Applied
Scientific EffectAnti-shrinkage:

Data Source

PatentUS11124452B2Non-aqueous liquid anti-shrinkage cement additives
Publication Date: 2021.09.21 HALLIBURTON ENERGY SERVICES INC
  • US11124452B2 patent drawing
  • US11124452B2 patent drawing

AI summary

The present disclosure relates to a method of cementing comprising: providing a cement composition comprising: water, a cement, and a non-aqueous liquid anti-shrinkage cement additive comprising calcined magnesium oxide and a non-aqueous liquid; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. Non-aqueous liquid anti-shrinkage cement additives, cement compositions, and systems are also provided.