Heat pump device using a non-azeotropic mixture refrigerant

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Heat pump devices using non-azeotropic mixture refrigerants face challenges in accurately detecting and controlling the composition ratio, which can lead to increased flammability and disproportionation reactions due to changes in refrigerant composition during operation.

Innovation Solution

A heat pump device with a refrigerant circuit including a compressor, four-way switching valve, condenser, expansion mechanisms, and a container equipped with temperature and pressure measurement units, allowing the control unit to estimate the physical properties of the non-azeotropic mixture refrigerant based on temperature and pressure measurements, thereby controlling the composition ratio and preventing adverse reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a non-azeotropic mixture refrigerant is used in a heat pump device, then the refrigeration efficiency is improved, but the composition ratio of the refrigerant changes during operation leading to increased flammability and disproportionation reactions

Engineering Contradiction:
Improverefrigeration efficiencyVSAvoidrefrigerant composition stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The system continuously monitors the temperature and pressure of the refrigerant in the accumulator, uses these measurements to estimate the composition ratio through a refrigerant property calculation unit, and feeds this information back to the control unit which adjusts the expansion valve opening degree to maintain safe operating conditions

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent replaces direct chemical analysis methods with a physical measurement-based estimation system, using temperature and pressure sensors combined with refrigerant property calculations to determine composition ratio, avoiding the need for complex chemical detection equipment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If the composition ratio of the non-azeotropic mixture refrigerant is not controlled, then flammability increases and disproportionation reactions occur, but implementing composition detection and control increases device complexity

Engineering Contradiction:
Improvesafety against flammability and disproportionationVSAvoiddetection and control system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The system introduces a refrigerant property calculation unit as an intermediary that computes the composition ratio from readily available temperature and pressure measurements, serving as a bridge between simple physical measurements and the required composition information without requiring direct chemical sensing

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system creates a virtual model of the refrigerant composition by calculating it from temperature and pressure data, rather than directly measuring the actual composition, using the relationship between physical properties and composition to generate an accurate representation of the refrigerant state

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables precise estimation and control of the refrigerant composition, reducing flammability risks and preventing disproportionation reactions, ensuring safe and efficient operation of the heat pump device.

Implementation Method 1

The temperature measurement unit measures a temperature of the non-azeotropic mixture refrigerant in the container

Methodology Applied
Scientific EffectThermal energy transfer: Conduction (thermal)

Implementation Method 2

The pressure measurement unit measures a pressure of the non-azeotropic mixture refrigerant in the container

Methodology Applied
Scientific EffectGas pressure: Pressure Increase

Implementation Method 3

the control unit estimates a composition ratio of the non-azeotropic mixture refrigerant circulating in the refrigerant circuit based on the temperature and the pressure of the non-azeotropic mixture refrigerant accumulated in the container

Methodology Applied
Scientific EffectTemperature-pressure composition relationship: Phase Change

Data Source

PatentUS12044452B2Heat pump device using a non-azeotropic mixture refrigerant
Publication Date: 2024.07.23 DAIKIN INDUSTRIES LTD
  • US12044452B2 patent drawing
  • US12044452B2 patent drawing
  • US12044452B2 patent drawing

AI summary

In an air conditioner, during an operation, a gas-liquid two-phase non-azeotropic mixture refrigerant enters a receiver and accumulates in the receiver in a state where a gas phase and a liquid phase are separated. For example, when the non-azeotropic mixture refrigerant includes two components, i.e., a high-boiling refrigerant and a low-boiling refrigerant, the controller may estimate the ratio (composition ratio) between the low-boiling refrigerant and the high-boiling refrigerant in each of the gas phase and the liquid phase based on the temperature and the pressure of the non-azeotropic mixture refrigerant in the receiver. Thus, the controller may estimate the composition ratio of the liquid-phase non-azeotropic mixture refrigerant flowing out of the receiver as the composition ratio of the non-azeotropic mixture refrigerant circulating in the refrigerant circuit.