Non-dusting Effect Pigment Pellets for Powder Coatings

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Solution Overview

Problem

Powder coatings face challenges with the dispersion and orientation of effect pigments like aluminum flakes and pearlescent pigments due to their susceptibility to bending and breakage under high shear mixing, leading to poor appearance and safety hazards from dust generation, which often results in outsourcing the bonding of fine metallic pigments.

Innovation Solution

A pigment pellet preparation comprising effect pigments dispersed in a thermosetting resin with 3 or more reactive terminal groups, formulated to be non-dusting and available in a pelletized form, allowing safe bonding and incorporation into powder coatings without degradation, reducing manufacturing steps and enhancing safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If effect pigments are incorporated during extrusion and/or milling steps, then the pigment is mixed into the resin, but the effect pigments are damaged and their appearance suffers

Engineering Contradiction:
Improvepigment incorporation processVSAvoidpigment appearance quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The effect pigments are pre-dispersed in the thermosetting resin before extrusion, creating a master batch where the pigment is already properly oriented and protected. This preliminary dispersion prevents damage during subsequent processing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The manufacturing process is divided into separate stages: first creating a pigment-resin master batch with proper pigment orientation, then incorporating this protected pigment into the final powder coating formulation, avoiding direct exposure to high-shear mixing.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If solvent free effect pigment powder is used, then the powder coating can be made, but a large release of dust is generated causing inhalation hazards and explosion risks

Engineering Contradiction:
Improvepowder coating productionVSAvoiddust inhalation and explosion hazards
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The effect pigments are encapsulated within a thermosetting resin matrix, forming a protective shell around each pigment particle. This encapsulation prevents dust generation while allowing the pigment to function normally when the coating is applied and cured.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

A composite pigment preparation is created by combining effect pigments with thermosetting resin in a controlled dispersion. This composite form maintains the functional properties of the effect pigment while eliminating the dust hazards associated with loose pigment powder.

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If effect pigments with large aspect ratios are used, then the color and appearance are enhanced, but the pigments are very susceptible to bending and breakage under high shear mixing

Engineering Contradiction:
Improvecolor and appearance effectVSAvoidpigment structural integrity
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The high-aspect-ratio effect pigments are pre-oriented and dispersed in the resin before the extrusion process, establishing their optimal positioning and protecting their structural integrity before they are subjected to any mechanical stress.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The thermosetting resin acts as an intermediary medium that supports and protects the fragile high-aspect-ratio pigment structures during processing, allowing them to maintain their shape and optical properties without direct mechanical stress.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pigment pellet preparation maintains the appearance of effect pigments, eliminates dust-related hazards, and streamlines the manufacturing process by enabling safe and efficient incorporation into powder coatings, reducing cure time and allowing for high formulation flexibility.

Implementation Method 1

The thermosetting resin has 3 or more reactive terminal groups

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

The effect pigment is dispersed in the thermosetting resin

Methodology Applied
Scientific EffectDispersion: Suspension

Data Source

PatentEP3500630B1Non-dusting effect pigment preparation for powder coating composition
Publication Date: 2020.06.24 SUN CHEMICAL CORP

AI summary

A pigment pellet preparation, comprises one or more effect pigment and one or more thermosetting resin. The effect pigment is dispersed in the thermosetting resin. The thermosetting resin has 3 or more reactive terminal groups and has an acid number from about 10 to about 50 mg KOH/g resin. The preparation comprises from about 70% to about 90% by weight of one or more effect pigment and from about 5% to about 35% by weight of one or more thermosetting resin. The pigment and thermosetting resin comprise about 95% or more of the preparation. The pellets have a diameter of about 0.5 mm to about 5 mm and a length of about 1 mm to about 5 cm.