Non-aqueous Ink Jet Composition for Discharge Stability
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Solution Overview
Problem
Existing ink jet recording methods face challenges in achieving sufficient discharge stability and covering ability, particularly with oil-based white ink compositions, as they often suffer from pigment aggregation and uneven drying properties.
Innovation Solution
A non-aqueous ink jet ink composition is developed, comprising a white pigment with an average particle diameter of 200-400 nm, glycol diether with a flash point of 70° C. or less, and glycol monoether, optimized in weight percentage and ratio, along with cyclic lactone and vinyl chloride resin, to enhance discharge stability and covering ability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Stability of the object's composition
If conventional oil-based white ink composition is used, then long-term storage stability is improved, but discharge stability and covering ability are insufficient
Solution Approach 1:
The patent changes the particle size parameter of white pigment to 200-400 nm and adjusts solvent composition parameters (glycol diether content: 40-90 wt%, glycol monoether content: 20 wt% or less) to achieve both long-term storage stability and discharge stability. This parameter optimization resolves the contradiction by finding the optimal balance point where pigment aggregation is prevented during storage while maintaining stable discharge performance.
Solution Approach 2:
The patent uses a composite solvent system combining glycol diether and glycol monoether in specific proportions, along with composite pigment structures (white pigment particles in the 200-400 nm range). This composite approach allows the ink composition to simultaneously achieve long-term storage stability and discharge stability by leveraging the complementary properties of different materials in the composite system.
2Stability of the object's composition
If conventional oil-based white ink composition is used, then long-term storage stability is improved, but covering ability is insufficient
Solution Approach 1:
The patent optimizes the particle size parameter of white pigment to 200-400 nm, which is the critical parameter for achieving adequate covering ability. This parameter change ensures that pigment particles are small enough to disperse uniformly and provide good coverage, while still maintaining long-term storage stability. The specific particle size range prevents aggregation that would compromise either covering ability or storage stability.
Solution Approach 2:
The patent applies local quality by using glycol monoether specifically to control the local properties of the ink composition related to covering ability. The glycol monoether (content: 20 wt% or less) specifically influences the dispersion and coverage characteristics of the white pigment, while the glycol diether handles the bulk stability requirements. This localized functional assignment resolves the contradiction between storage stability and covering ability.
3Manufacturing precision
If white pigment with smaller particle diameter is used, then covering ability is improved, but discharge stability deteriorates
Solution Approach 1:
The patent identifies and optimizes the critical parameter of white pigment particle diameter to the specific range of 200-400 nm. This parameter optimization resolves the contradiction by finding the optimal balance point where particles are small enough for good covering ability (better than conventional larger particles) but not so small as to cause aggregation and discharge instability. The specific particle size range represents the optimal compromise between these two opposing requirements.
Solution Approach 2:
The patent effectively 'copies' or replicates the successful particle size distribution characteristics of conventional stable inks while improving upon them by using 200-400 nm particles instead of larger conventional particles. This allows the ink to achieve both discharge stability (by copying the stability approach) and improved covering ability (by using smaller particles).
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition achieves improved discharge stability and covering ability, suppressing pigment aggregation and ensuring uniform drying, resulting in high-quality recorded matter with enhanced abrasion resistance.
Implementation Method 1
a non-aqueous ink jet ink composition containing a white pigment having an average particle diameter of 200 nm or more and 400 nm or less, glycol diether... and glycol monoether... to enhance discharge stability and covering ability
Implementation Method 2
glycol diether represented by the following formula 1... and glycol monoether represented by the following formula 2
Implementation Method 3
glycol diether having a flash point of 70° C. or less... ensuring uniform drying
Implementation Method 4
glycol diether having a flash point of 70° C. or less
Implementation Method 5
white pigment having an average particle diameter of 200 nm or more and 400 nm or less... covering ability
Data Source
AI summary
A non-aqueous ink jet ink composition contains a white pigment having an average particle diameter of 200 nm or more and 400 nm or less, glycol diether represented by the following formula 1 and having a flash point of 70° C. or less, and glycol monoether represented by the following formula 2:R1O—(R2O)m—R3 Formula 1:(In Formula 1, R1 and R3 each independently represent alkyl groups having 1 to 4 carbon atoms, R2 each independently represents alkylene groups having 2 to 3 carbon atoms, and m is an integer of 1 to 4.); andHO—(R4O)n—R5 Formula 2:(In Formula 2, R4 each independently represents alkylene groups having 2 to 3 carbon atoms, R5 is an alkyl group having 1 to 4 carbon atoms, and n is an integer of 1 to 4.).