Nonaqueous Inkjet Ink Composition for Particle Redispersion

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Solution Overview

Problem

Inkjet inks containing inorganic particles face issues with sedimentation during storage, leading to difficulty in redispersing settled particles, which affects discharge stability and nozzle integrity.

Innovation Solution

A nonaqueous inkjet ink formulation comprising inorganic particles and silicone resin particles with specific size ratios and properties that enhance redispersibility, fluidity, and nozzle protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If inorganic particles are used in inkjet ink, then the ink provides desired functional properties (whiteness, conductivity), but the inorganic particles easily settle during storage

Engineering Contradiction:
Improvefunctional propertiesVSAvoidparticle suspension stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces a polymer compound as an intermediary substance that specifically interacts with inorganic particles to prevent their aggregation and settlement. The polymer acts as a mediator between the inorganic particles and the ink medium, providing steric or electrostatic stabilization that maintains particle dispersion throughout storage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical and physical parameters of the ink system by selecting polymers with specific molecular weights, functional groups, and hydrophilic-lipophilic balances. These parameter changes optimize the polymer's ability to adsorb onto inorganic particle surfaces and provide repulsive forces that prevent settlement.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If inorganic particles settle, then storage stability is reduced, but redispersing the settled particles becomes difficult

Engineering Contradiction:
Improvestorage stabilityVSAvoidredispersibility
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent applies preliminary action by incorporating the polymer compound into the ink formulation before any settlement can occur. The polymer pre-coats the inorganic particle surfaces and establishes protective barriers that prevent strong aggregation, making future redispersion much easier if settlement does occur during storage.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The polymer compound serves as a mediator that remains associated with the inorganic particles even after settlement. This intermediary substance provides a lubricating or repulsive effect that reduces the strength of particle-particle interactions, enabling easy redispersion through gentle agitation without requiring harsh reprocessing.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If inorganic particles are used, then the ink achieves desired properties, but discharge stability deteriorates due to sedimentation

Engineering Contradiction:
Improvefunctional propertiesVSAvoiddischarge stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The polymer compound acts as an intermediary that maintains uniform particle distribution in the ink, ensuring consistent discharge characteristics. By preventing particle aggregation and settlement, the polymer mediator ensures that each discharge contains the intended concentration and distribution of functional inorganic particles.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes parameters such as polymer concentration, molecular weight, and functional group composition to achieve the right balance between preventing settlement and maintaining discharge stability. These parameter adjustments ensure that the ink flows consistently while keeping inorganic particles uniformly dispersed.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If inorganic particles are used in inkjet ink, then functional properties are provided, but nozzle damage increases due to sedimentation

Engineering Contradiction:
Improvefunctional propertiesVSAvoidnozzle damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies beforehand cushioning by having the polymer compound pre-protect the inorganic particle surfaces before they can settle and aggregate into harmful deposits. This protective polymer layer acts as a cushion that prevents direct particle-to-nozzle contact and reduces mechanical damage during the discharge process.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The polymer compound serves as a protective intermediary between the inorganic particles and the nozzle components. This mediator layer reduces friction and mechanical stress during particle discharge, preventing wear and damage to the delicate nozzle structures while still allowing functional particles to be delivered.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation effectively prevents sedimentation and facilitates easy redispersement of inorganic particles, maintaining discharge stability and reducing nozzle damage.

Implementation Method 1

the inorganic particles easily settle in the ink during storage or waiting before discharge

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Implementation Method 2

redispersibility of inorganic particles that have settled

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentEP4435064B1Nonaqueous inkjet ink and method for forming cured product
Publication Date: 2026.04.22 KONICA MINOLTA INC
  • EP4435064B1 patent drawing
  • EP4435064B1 patent drawing
  • EP4435064B1 patent drawing

AI summary

To provide a nonaqueous inkjet ink having excellent redispersibility of inorganic particles that have settled. A nonaqueous inkjet ink includes inorganic particles and silicone resin particles. The silicone resin particles have an average particle size of 0.3 µm or more and 10 µm or less, and the average particle size of the silicone resin particles is smaller than a median diameter of the inorganic particles.