Non-resonant Two-Photon Absorption Recording Material

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Solution Overview

Problem

Current non-resonant two-photon absorption recording materials lack high humidity/heat resistance and sufficient recording/readout characteristics, especially when using recording light with wavelengths shorter than 700 nm for forming smaller pits.

Innovation Solution

A non-resonant two-photon absorption recording material incorporating a polymer compound with specific structures, such as those represented by formulas (1) to (4), which includes polystyrene, polyacrylate, or polymethacrylate as the main chain, and a copolymer component, along with a refractive index or fluorescence intensity-modulating material, to enhance recording performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If non-resonant two-photon absorption recording materials are used with shorter wavelengths (shorter than 700 nm) to achieve higher recording density and smaller pits, then recording density is improved, but humidity/heat resistance deteriorates

Engineering Contradiction:
Improverecording densityVSAvoidhumidity/heat resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent employs composite materials by combining specific polymer compounds (polystyrene, polyacrylate, or polymethacrylate main chains with copolymer components) with refractive index or fluorescence intensity-modulating materials. This composite structure enables the material to simultaneously achieve high recording density through non-resonant two-photon absorption at shorter wavelengths and maintain high humidity/heat resistance, resolving the technical contradiction between recording precision and environmental stability.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If non-resonant two-photon absorption is used to achieve spatial resolution enhancement and three-dimensional recording, then manufacturing precision is improved, but the material requires specific structural complexity

Engineering Contradiction:
Improvespatial resolutionVSAvoidmaterial structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies local quality by designing polymer compounds with specific local structural features: main chains consisting of polystyrene, polyacrylate, or polymethacrylate with copolymer components containing electron-donating groups and electron-withdrawing groups at specific positions. This localized structural design enables non-resonant two-photon absorption capability and spatial resolution enhancement while maintaining overall material processability and reducing unnecessary structural complexity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables high humidity/heat resistance and improved recording density with the ability to perform non-resonant two-photon absorption using shorter wavelengths, ensuring effective readout and recording capabilities.

Implementation Method 1

In the case where the two-photon absorption occurs in the energy region having no (linear) absorption band of the compound, this is called non-resonant two-photon absorption

Methodology Applied
Scientific EffectNon-resonant two-photon absorption: Absorption (EM radiation)

Implementation Method 2

a refractive index or fluorescence intensity-modulating material, to enhance recording performance

Methodology Applied
Scientific EffectRefractive index modulation: Refraction

Data Source

PatentUS9159356B2Non-resonant two-photon absorption recording material, non-resonant polymer two-photon absorption optical information recording medium, and recording/reproducing method
Publication Date: 2015.10.13 FUJIFILM CORP
  • US9159356B2 patent drawing
  • US9159356B2 patent drawing
  • US9159356B2 patent drawing

AI summary

The present invention provides a non-resonant two-photon absorption recording material containing a non-resonant polymer two-photon absorption compound, and the non-resonant two-photon absorption recording material wherein the main chain of the non-resonant polymer two-photon absorption compound contains at least one member selected from polystyrene, polyacrylate, polymethacrylate-polyester, polyurethane, polyether and polyimide, and also provides an optical information recording medium having a recording layer containing the recording material.