Nonwoven Fabric Separator for Lead Storage Battery Stratification

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Solution Overview

Problem

Lead storage batteries face challenges in maintaining long cycle life, high capacity, and low resistance due to stratification phenomena caused by concentration differences in sulfuric acid within the battery cells, which existing separators fail to adequately address.

Innovation Solution

A nonwoven fabric separator composed of recycled or synthetic fibers with specific pore diameter and porosity ranges, including ultrafine and thermoplastic resin fiber layers, is developed to enhance ion permeability, chemical stability, and mechanical strength, preventing sulfate ion precipitation and stratification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If glass fiber is used in the separator to suppress stratification, then sulfate ion adsorption effect is improved, but the separator becomes poor in flexibility and susceptible to shock

Engineering Contradiction:
Improvestratification suppressionVSAvoidflexibility and shock resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The separator uses a composite structure combining glass fiber nonwoven fabric (for sulfate ion adsorption) with polyolefin nonwoven fabric layers (for flexibility and shock resistance). This composite material approach allows the separator to simultaneously achieve stratification suppression through glass fiber while maintaining mechanical flexibility through the polyolefin layers.

Inventive Principle:
Principle #40Composite materials

2Reliability

If ultrafine fiber nonwoven fabric is used to control pore diameter, then ion permeability is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improveion permeabilityVSAvoidpore diameter control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The separator utilizes ultrafine fiber nonwoven fabric with controlled pore diameters (0.03-10 μm) to achieve high ion permeability. The porous structure allows efficient ion transport while the specific pore size distribution is optimized to balance performance with manufacturing feasibility.

Inventive Principle:
Principle #31Porous materials

3Duration of action of stationary object

If the separator structure is optimized for long cycle life, then stratification prevention is improved, but battery capacity and output may be compromised

Engineering Contradiction:
Improvecycle lifeVSAvoidcapacity and output
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The separator employs a multi-layer structure where each layer has specific local functions: the glass fiber layer targets sulfate ion adsorption and stratification prevention, the polyolefin layers provide mechanical strength and flexibility, and the ultrafine fiber layer optimizes ion permeability. This local quality differentiation allows the separator to simultaneously achieve long cycle life through stratification control while maintaining high capacity and output through optimized ion transport pathways.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The separator effectively prolongs the cycle life of lead storage batteries by maintaining high ion conductivity and preventing stratification, ensuring stable battery performance and low resistance.

Implementation Method 1

the effect of silica on sulfate ion adsorption suppresses stratification

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a nonwoven fabric separator for a lead storage battery, characterized in that a relationship between an average pore diameter (D) of the nonwoven fabric separator and a number of pores (N) satisfies the following equation (1)

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentEP3425697B1Nonwoven fabric separator for lead storage battery, and lead storage battery using same
Publication Date: 2020.09.16 ASAHI KASEI KOGYO KABUSHIKI KAISHA
  • EP3425697B1 patent drawing
  • EP3425697B1 patent drawing
  • EP3425697B1 patent drawing

AI summary

A nonwoven fabric separator for a lead storage battery includes a nonwoven fabric configured with regenerated fibers or synthetic fibers.