Novolak Phenolic Epoxy Resin for Reliable Chip Bonding

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Solution Overview

Problem

Conventional non-conductive films (NCFs) used in packaging electronic components on printed circuit boards face issues with connection reliability due to fast curing initiation by imidazole-based epoxy resin compositions, which can result in insufficient reliability and transparency, making it difficult to visually check alignment marks.

Innovation Solution

The use of a novolak phenolic curing agent and an acrylic elastomer copolymer containing dimethyl acrylamide and hydroxyethyl methacrylate, combined with an inorganic filler, in the epoxy resin composition slows down curing initiation and enhances transparency, ensuring high connection reliability and ease of alignment mark recognition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If imidazole-based epoxy resin composition is used, then curing initiation becomes faster, but connection reliability becomes insufficient

Engineering Contradiction:
Improvecuring initiation speedVSAvoidconnection reliability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the curing agent system, replacing pure imidazole with a combination of novolak phenolic curing agent and imidazole. This parameter change slows down the curing initiation speed while maintaining adequate connection reliability, resolving the contradiction between fast curing and reliable connection.

Inventive Principle:
Principle #35Parameter changes

2Speed

If imidazole-based epoxy resin composition is used, then curing initiation becomes faster, but transparency deteriorates

Engineering Contradiction:
Improvecuring initiation speedVSAvoidtransparency
Core Design Contradiction:
SpeedVSIllumination intensity

Solution Approach 1:

The patent modifies the chemical composition parameters by introducing novolak phenolic curing agent alongside imidazole, which changes the curing kinetics to be slower and produces a more transparent cured product. This resolves the contradiction between fast curing initiation and transparency by adjusting the compositional parameters.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution achieves excellent connection reliability and transparency, allowing for reliable bonding and easy alignment mark recognition, as demonstrated by improved bonding strength and resistance to wet heat reflow.

Implementation Method 1

the reaction of curing initiation becomes faster, with the consequence that sufficient connection reliability may not be achieved

Methodology Applied
Scientific EffectCuring reaction: Chemical Bonding

Implementation Method 2

an acrylic elastomer, an epoxy resin and an inorganic filler, wherein the acrylic elastomer is a copolymer containing dimethylacrylamide and hydroxyethyl methacrylate

Methodology Applied
Scientific EffectCopolymerization: Chemical Bonding

Data Source

PatentUS8802776B2Epoxy resin composition, method for producing composite unit using the epoxy resin composition, and composite unit
Publication Date: 2014.08.12 DEXERIALS CORP
  • US8802776B2 patent drawing
  • US8802776B2 patent drawing
  • US8802776B2 patent drawing

AI summary

An epoxy resin composition having excellent connection reliability and transparency, a method for manufacturing a composite unit using the epoxy resin composition, and the composite unit, are disclosed. The manufacturing method includes an attaching step of attaching an epoxy resin composition (2) containing a novolak phenolic curing agent, an acrylic elastomer composed of a copolymer containing dimethylacrylamide and hydroxylethyl methacrylate, an epoxy resin and not less than 5 parts by weight to not more than 20 parts by weight of an inorganic filler to 100 parts by weight of the epoxy resin, to a printed circuit board (1) in the form of a sheet. The manufacturing method also includes a temporary loading step of temporarily loading a semiconductor chip (3) and capacitors (4a) to (4d) on the epoxy resin composition (2) and an ultimate pressure bonding step of pressuring the semiconductor chip (3) and capacitors (4a) to (4d) by a thermal bonding head (20) in situ to ultimately pressure bond the semiconductor chip (3) and capacitors (4a) to (4d).