Nanoengineered Particulate Coatings for Citrus Crop Protection

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Solution Overview

Problem

Current particle film technologies for insect control, such as those using kaolin clays, face limitations including gaps in coverage as leaves grow, poor adhesion to fresh flush, and lack of rain fastness, which compromise their effectiveness in protecting citrus crops from Asian Citrus Psyllid and Huanglongbing disease.

Innovation Solution

Nanoengineered particulate coatings (NPCs) are developed, comprising hydrophobic clay particles that encapsulate insect repellents and dyes, allowing for slow and extended release, improved adhesion, and weather resistance, including the use of cationic surfactants to modify montmorillonite clays for enhanced hydrophobic properties and encapsulation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional particle film technology is used for insect control, then initial coverage is achieved, but gaps develop as leaves grow and adhesion to fresh flush is poor

Engineering Contradiction:
Improveprotection continuityVSAvoidprotection duration
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The particle film formulation is designed to be dynamic, allowing it to flow and redistribute in response to leaf growth and environmental conditions. The particles maintain mobility within the film matrix, enabling them to fill gaps as leaves expand and re-adhere to fresh flush, thus maintaining continuous protection throughout the plant's growth cycle.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention modifies key parameters of traditional particle films by incorporating specific adhesion promoters and adjusting particle size distribution. These parameter changes enhance the film's ability to adhere to both mature and fresh leaves, preventing gap formation and maintaining reliable protection as the plant grows.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional particle films are applied, then initial insect repellency is achieved, but rain fastness is lacking and weather resistance is poor

Engineering Contradiction:
Improveinsect protection effectivenessVSAvoidfilm persistence
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention creates a composite particle film formulation by combining traditional kaolin particles with polymer binders, adhesion promoters, and hydrophobic agents. This composite structure provides both effective insect repellency and enhanced weather resistance, as the different components work synergistically to maintain film integrity during rain and wind while preserving biological activity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The formulation incorporates localized functional components: hydrophobic agents are concentrated at the film's outer surface to provide water repellency, while adhesion promoters are distributed throughout to ensure strong bonding to leaf surfaces. This local quality differentiation allows the film to simultaneously achieve rain fastness and reliable insect protection.

Inventive Principle:
Principle #3Local quality

3Reliability

If frequent particle film applications are made to maintain protection, then continuous coverage is achieved, but application cost and labor increase

Engineering Contradiction:
Improveprotection continuityVSAvoidapplication efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The enhanced particle film formulation provides continuous protective action for extended periods (3-6 months) by maintaining film integrity and biological activity throughout the application season. This continuity eliminates the need for frequent reapplications, significantly improving application efficiency while maintaining reliable insect protection.

Inventive Principle:
Principle #20Continuity of useful action

4Object-affected harmful factors

If particle films are used to protect citrus crops, then insect attack is reduced, but adhesion to fresh flush and rain fastness remain insufficient

Engineering Contradiction:
Improveinsect damageVSAvoidfilm adhesion and persistence
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention introduces polymer binders and adhesion promoters as intermediary substances between the particle film and the leaf surface. These intermediaries create strong bonding interfaces that ensure reliable adhesion to both mature and fresh flush leaves, while also providing a protective matrix that enhances rain fastness and maintains film persistence in citrus orchards.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

NPCs provide continuous protection against insect attacks during leaf growth, adhere well to both mature and fresh leaves, and withstand weather fluctuations, offering extended release of repellents up to several months, significantly improving the durability and effectiveness of insect control compared to traditional methods.

Implementation Method 1

Nanoengineered particulate coatings (NPCs) are developed, comprising hydrophobic clay particles that encapsulate insect repellents and dyes, allowing for slow and extended release

Methodology Applied
Scientific EffectEncapsulation:

Implementation Method 2

allowing for slow and extended release, improved adhesion, and weather resistance, including the use of cationic surfactants to modify montmorillonite clays for enhanced hydrophobic properties and encapsulation

Methodology Applied
Scientific EffectControlled release:

Implementation Method 3

including the use of cationic surfactants to modify montmorillonite clays for enhanced hydrophobic properties and encapsulation

Methodology Applied
Scientific EffectSurface modification:

Implementation Method 4

hydrophobic clay particles that encapsulate insect repellents

Methodology Applied
Scientific EffectHydrophobic modification: Hydrophobe

Implementation Method 5

The main effect of a particle film barrier on plant foliage is to interfere with the visual cues as well as ability of insects to settle, feed, move, and oviposit

Methodology Applied
Scientific EffectPhysical barrier: Physical Containment

Data Source

PatentUS9936692B2Engineered particulate systems for controlled release of pesticides and repellants
Publication Date: 2018.04.10 UNIV OF FLORIDA RESEARCH FOUNDATION INC
  • US9936692B2 patent drawing
  • US9936692B2 patent drawing
  • US9936692B2 patent drawing

AI summary

Nanoengineered particulate coatings (NPCs) comprise a multiplicity of particulate hosts that are infused with a nanophase comprising a surfactant and at least one guest. The particulate hosts can be clay particles, the surfactant can be a cationic surfactant, and the guest can be an insect repellant. For example, montmorillonite particles infused with hexadecyl trimethyl ammonium bromide and garlic oil form NPCs that may be used to form an emulsion or suspension for spraying on citrus trees to repel Asian Citrus Psyllid.