Particulate Nucleating Agent Phosphate Control for Polyolefin Coloring

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Solution Overview

Problem

The existing nucleating agents for polyolefin-based resins face issues with feed reliability and color tone when added to polyolefin-based resins, leading to compromised production reliability and undesirable coloring of molded products.

Innovation Solution

A particulate nucleating agent containing an aromatic phosphate ester metal salt, specifically within a controlled range of phosphate ion content, is used to enhance feed reliability and suppress coloring, achieved through the synthesis and formulation of compounds like those represented by General Formula (1) and their combination with other components such as fatty acid metal salts and silicic acid-based inorganic additives.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phosphate ions are added to improve feed reliability, then feed reliability is improved, but excessive phosphate ions cause coloring of the molded product

Engineering Contradiction:
Improvefeed reliabilityVSAvoidcoloring of molded product
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by precisely controlling the phosphate ion content within a specific range (5-500 ppm). This quantitative parameter control resolves the contradiction by finding the optimal value that simultaneously improves feed reliability while preventing excessive coloring, transforming the harmful effect into a controlled and acceptable level.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs partial action by adding phosphate ions in controlled, limited amounts rather than excessive quantities. By implementing partial action with precise dosage control within the specified range, the patent achieves the beneficial effect of improved feed reliability while avoiding the harmful excessive coloring effect.

Inventive Principle:
Principle #16Partial or excessive action

2Manufacturing precision

If a particulate nucleating agent is added to improve crystallization properties, then crystallization temperature and transparency are improved, but feed reliability and production reliability deteriorate

Engineering Contradiction:
Improvecrystallization temperature and transparencyVSAvoidfeed reliability and production reliability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by controlling particle size distribution and phosphate ion content of the nucleating agent. These parameter optimizations enable the material to simultaneously achieve good crystallization properties and feed reliability, resolving the contradiction between manufacturing precision and production reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by formulating a nucleating agent that combines aromatic phosphate ester metal salts with specific particle size distribution and controlled phosphate ion content. This composite approach integrates multiple functional characteristics into one material that simultaneously improves crystallization properties while maintaining feed reliability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively improves feed reliability and maintains the color tone of molded products, allowing for enhanced production reliability and improved physical properties like crystallization temperature and transparency.

Implementation Method 1

a technique of adding a crystal nucleating agent or a crystallization accelerator is known

Methodology Applied
Scientific EffectNucleation: Nucleation

Data Source

PatentEP3964547B1Particulate nucleating agent, resin composition, production method thereof, and molded product
Publication Date: 2024.09.25 ADEKA CORP
  • EP3964547B1 patent drawing
  • EP3964547B1 patent drawing
  • EP3964547B1 patent drawing

AI summary

A particulate nucleating agent of the present invention is a particulate nucleating agent that contains a compound represented by a predetermined general formula, in which a content of phosphate ions in the particulate nucleating agent, which is obtained by a predetermined measurement procedure, is equal to or more than 5 ppm and equal to or less than 8,000 ppm based on a mass of the compound represented by the predetermined general formula.