O-acyl isethionate surfactant blends for mild cleansing

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Solution Overview

Problem

The incorporation of high-melting, water-insoluble O-acyl isethionates in personal care formulations is challenging due to their high melting points and low solubility, requiring energy-intensive processes and the use of additional surfactants in liquid delivery systems, which can be costly and pose health hazards.

Innovation Solution

A cost-effective, energy-efficient process to produce blends of O-acyl isethionates and N-acyl amino acid surfactants from fatty acid chloride, allowing for flexible ratios and direct conversion of solid O-acyl isethionates into liquid form without additional surfactants, using a two-step reaction at controlled temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If O-acyl isethionates are incorporated in solid form, then formulation is simple, but high melting points require energy-intensive heating processes

Engineering Contradiction:
Improveease of incorporationVSAvoidenergy consumption
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent changes the physical state parameter of O-acyl isethionates from solid to liquid form through chemical modification or selection of specific derivatives, enabling incorporation at lower temperatures and reducing energy consumption while maintaining formulation simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses readily available fatty acid chlorides as starting materials to synthesize O-acyl isethionates in liquid form, eliminating the need for expensive liquid delivery systems and high-temperature processing equipment

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Ease of operation

If liquid delivery systems are used to solubilize O-acyl isethionates, then ease of incorporation improves, but additional surfactants increase cost and potential health hazards

Engineering Contradiction:
Improveease of incorporationVSAvoidhealth hazards
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates the need for additional surfactants by directly synthesizing O-acyl isethionates in liquid form that can be incorporated without solubilization aids, removing the harmful components while maintaining ease of incorporation

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The O-acyl isethionates are designed to be self-deliverable in liquid form, serving their own solubilization function without requiring additional surfactants or liquid delivery systems, thereby eliminating health hazards associated with extra ingredients

Inventive Principle:
Principle #25Self-service

3Reliability

If high levels of emollients are used for moisturization, then skin benefit improves, but formulation complexity and cost increase

Engineering Contradiction:
Improvemoisturization benefitVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent makes O-acyl isethionates serve multiple functions: as primary surfactants for cleansing and as emollients for moisturization, eliminating the need for separate emollient ingredients and simplifying the overall formulation while maintaining skin benefits

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables the creation of 'super-mild' personal cleansing compositions with improved ease of incorporation and reduced energy consumption, eliminating the need for high-temperature processing and excess surfactants, while ensuring safety and flexibility in formulation.

Implementation Method 1

reacting alkali metal or ammonium salts of hydroxyalkyl sulphonates with fatty acid chloride

Methodology Applied
Scientific EffectEsterification: Chemical Bonding

Implementation Method 2

reaction of the remainder fatty acid chloride with equivalent quantity of aqueous solution of one or more amino acids

Methodology Applied
Scientific EffectAmidation: Chemical Bonding

Data Source

PatentEP2882410B1Blends of o-acyl isethionates and n- acyl amino acid surfactants
Publication Date: 2017.09.27 GALAXY SURFACTANTS LTD
  • EP2882410B1 patent drawingFigure 1
  • EP2882410B1 patent drawingFigure 2
  • EP2882410B1 patent drawing

AI summary

The present invention discloses a process for preparing blends of O-acyl isethionates and N-acyl amino acid surfactants using common fatty acid chlorides, in quantitative yields. The blends are in liquid form or can be spray dried to obtain solid dried form.