Supercritical CO2 De-oiling of Oat Protein

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Solution Overview

Problem

Current methods for producing oat protein compositions face challenges such as high lipid content, use of organic solvents, and particle size issues, leading to rancidity, explosion hazards, and inefficient filtration in industrial processes.

Innovation Solution

A process involving a protein-rich suspension from oat starting material, amylase enzyme hydrolysis, pH adjustments, centrifugation, and optional ultra-high temperature treatment and homogenization to produce an oat protein composition with low lipid content (<10% by weight) and a mean particle size greater than 10 microns, without using organic solvents or surfactants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If organic solvents are used to remove lipids from oat flour, then lipid content is reduced, but explosion risks and residual solvent levels increase

Engineering Contradiction:
Improvelipid contentVSAvoidexplosion risks and residual solvent
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent extracts lipids from oat flour using supercritical CO2, which is then separated and removed from the system. The CO2 solvent is recovered and can be reused, eliminating residual solvent in the final product while achieving effective lipid removal.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent utilizes changes in pressure and temperature parameters to transition CO2 between supercritical and gaseous states. By controlling these parameters, the solvent can be used for extraction then easily removed by depressurization, avoiding explosion risks associated with organic solvents.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If supercritical CO2 extraction is used to achieve high de-oiling, then lipid content is reduced below 10%, but particle size decreases below 10 microns leading to dust formation and explosion hazard

Engineering Contradiction:
Improvelipid contentVSAvoiddust formation and explosion hazard
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent carefully controls pressure and temperature parameters during supercritical CO2 extraction to achieve lipid removal while maintaining particle integrity. By optimizing these parameters, the process removes lipids effectively without reducing particle size below 10 microns, thus avoiding dust formation.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If oats are de-oiled prior to milling, then rancidity is prevented, but process complexity and cost increase

Engineering Contradiction:
Improverancidity preventionVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts lipids from whole oats before milling using supercritical CO2, preventing rancidity in the final flour and protein products. This extraction step is performed on whole oats, simplifying the overall process compared to de-oiling after milling while ensuring product stability.

Inventive Principle:
Principle #2Taking out (Extraction)

4Reliability

If protein is ground to superfine size below 10 microns, then protein functionality is improved, but handling difficulty and filtration cost increase

Engineering Contradiction:
Improveprotein functionalityVSAvoidhandling and filtration
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent optimizes pressure and temperature parameters during supercritical CO2 extraction to maintain protein particle size above 10 microns. This parameter control preserves protein functionality while avoiding the handling and filtration problems associated with superfine powders.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively reduces lipid content, avoids explosion hazards, and produces a stable oat protein composition suitable for various industrial applications with improved handling and safety, maintaining protein functionality.

Implementation Method 1

adding an amylase enzyme to the protein-rich suspension of step 1, thereby hydrolyzing the starch of the protein-rich suspension

Methodology Applied
Scientific EffectEnzyme hydrolysis: Hydrolysis

Implementation Method 2

separating by centrifugation the protein-rich suspension of step 2 until obtaining a heavy layer comprising fibers and a light layer comprising proteins

Methodology Applied
Scientific EffectCentrifugal separation: Centrifugal Separation

Implementation Method 3

subjecting the oat protein composition to an ultra-high temperature treatment

Methodology Applied
Scientific EffectThermal treatment: Heating

Data Source

PatentUS20240060108A1Low lipid content oat protein composition without traces of organic solvent or surfactant
Publication Date: 2024.02.22 ROQUETTE FRERES SA

AI summary

The invention pertains to the field of oat protein compositions and production method thereof. In particular, the present invention is directed to an oat protein composition having low lipid content and which does not contain traces of organic solvent or surfactant and to the production method thereof.