Optically Clear Adhesive for 3D Display Lamination

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Solution Overview

Problem

The challenge in the field of optically clear adhesives is to develop a composition that effectively bonds display components with 3D features, such as thick ink steps and curved surfaces, while minimizing optical defects and assembly time, and ensuring durable bonding and stress relief in capacitive touch panel assemblies.

Innovation Solution

An adhesive composition comprising an alkyl (meth)acrylate ester with 4 to 18 carbon atoms, a hydrophilic copolymerizable monomer, and a free-radical generating initiator, which maintains a tan delta value of 0.5 to 1.0 between 25°C and 100°C, allowing for good wetting, stress relief, and bubble-free lamination, even with thick ink steps and complex geometries.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional adhesives are used for bonding display components with thick ink steps, then bonding strength may be achieved, but wetting of thick inks and complex geometries is poor

Engineering Contradiction:
Improvewetting capabilityVSAvoidoptical quality
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The adhesive composition modifies its physical parameters by maintaining high tan delta values across a broad temperature range (25°C to 100°C), enabling the adhesive to remain soft and flowable during assembly to achieve complete wetting of thick ink steps and curved surfaces, then maintains this softness during operation for stress relief

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive is formulated as a composite system combining multiple monomers and oligomers with complementary properties: the hydrophilic copolymerizable monomer provides wetting and adhesion, the alkyl (meth)acrylate ester contributes to softness and flexibility, and the free-radical initiator enables curing, creating a material that simultaneously achieves wetting, bonding, and stress relief

Inventive Principle:
Principle #40Composite materials

2Strength

If hard adhesives are used for bonding, then structural strength is improved, but stress relief and wetting of complex geometries deteriorate

Engineering Contradiction:
Improvebonding durabilityVSAvoidstress relief
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The adhesive maintains a tan delta value of 0.5 to 1.0 across a broad temperature range (25°C to 100°C), ensuring the material remains soft and compliant during both assembly and operational phases, providing continuous stress relief while maintaining bonding durability through proper formulation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive composition uses a specific ratio of soft monomers and oligomers to achieve excessive softness (high tan delta) that exceeds typical adhesive requirements, ensuring complete wetting of complex geometries and adequate stress relief, then cures to maintain this soft character for ongoing performance

Inventive Principle:
Principle #16Partial or excessive action

3Reliability

If long assembly cycle times are used, then complete bonding and defect elimination are achieved, but productivity decreases

Engineering Contradiction:
Improvebonding completenessVSAvoidassembly cycle time
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The adhesive composition is formulated to be ready-to-use at ambient temperatures with no preheating required, allowing immediate application and wetting of substrates, eliminating preparatory time and enabling rapid assembly while maintaining complete bonding through the adhesive's inherent flow characteristics

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The adhesive enables rapid assembly by skipping the traditional long curing cycles, achieving complete bonding and bubble elimination through its high tan delta values that promote rapid wetting and flow into complex geometries, then maintaining this performance with short cycle times

Inventive Principle:
Principle #21Skipping (Rushing through)

4Ease of manufacture

If air gaps are present between display components, then assembly simplicity is maintained, but optical quality deteriorates

Engineering Contradiction:
Improveassembly simplicityVSAvoidoptical quality
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The adhesive's high tan delta values (0.5 to 1.0) across a broad temperature range enable the material to flow and fill air gaps completely during assembly, eliminating internal reflecting surfaces that degrade optical quality, while maintaining assembly simplicity through its ready-to-use formulation requiring no special processing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive composition enables efficient lamination with short cycle times, durable bonding, and reduced optical defects, as evidenced by high tan delta values indicating good flow characteristics and improved substrate adhesion, resulting in a bubble-free laminate with enhanced optical quality and shock resistance.

Implementation Method 1

An adhesive composition includes an alkyl (meth)acrylate ester, a hydrophilic copolymerizable monomer and a free-radical generating initiator

Methodology Applied
Scientific EffectFree-radical polymerization: Photopolymerisation

Implementation Method 2

The adhesive composition maintains a tan delta value of between about 0.5 to about 1.0 at a temperature of between about 25° C. and about 100° C.

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

They can improve stress relief as a result of the display module assembly process

Methodology Applied
Scientific EffectStress relaxation: Stress Relaxation

Data Source

PatentUS9879161B2Optically clear adhesive, method of use and articles therefrom
Publication Date: 2018.01.30 3M INNOVATIVE PROPERTIES CO
  • US9879161B2 patent drawing
  • US9879161B2 patent drawing

AI summary

An adhesive composition includes an alkyl (meth)acrylate ester, wherein the alkyl group has 4 to 18 carbon atoms, a hydrophilic copolymerizable monomer and a free-radical generating initiator. The adhesive composition has a tan delta value of between about 0.5 and about 1.0 at a temperature of between about 25 C and about 100 C.