OCTG Threaded Connection Coating for White Rust and Galling Resistance

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Solution Overview

Problem

Oil country tubular goods stored outdoors for long periods often experience white rust, leading to decreased galling resistance and sealability of threaded connections, which existing compositions and lubricant coatings fail to adequately address.

Innovation Solution

A threaded connection method involving a Zn—Ni alloy plating layer followed by a chromate coating, with specific conditions such as a stirring speed of 0.5 m/s or more, chromate treatment time less than 50 seconds, and drying temperature of 60° C. or less, to enhance corrosion resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If heavy metal-containing compound greases are used to improve galling resistance, then galling resistance is improved, but environmental harm increases due to heavy metal contamination

Engineering Contradiction:
Improvegalling resistanceVSAvoidenvironmental harm from heavy metals
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes the harmful heavy metal components from the grease formulation while retaining the essential lubricating and anti-galling functions through alternative chemical compositions that are environmentally benign

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs alternative grease compositions that, while potentially requiring more frequent application or having different service life characteristics, eliminate the need for environmentally harmful heavy metals, thus trading long-term environmental damage for shorter-term operational considerations

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If grease-free threaded connections are used to eliminate heavy metal contamination, then environmental harm is reduced, but galling resistance deteriorates

Engineering Contradiction:
Improveenvironmental harm from heavy metalsVSAvoidgalling resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical parameters and composition of the grease formulation, replacing heavy metal compounds with alternative substances that provide similar lubricating and protective functions without the harmful environmental effects, thereby maintaining galling resistance in an environmentally friendly manner

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional plating and coating methods are used on threaded connections, then manufacturing simplicity is maintained, but corrosion resistance deteriorates when stored outdoors for long periods

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcorrosion resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs composite plating and coating structures that combine multiple materials with complementary properties, creating a layered system that provides superior corrosion resistance while maintaining compatibility with existing manufacturing processes and overall structural integrity

Inventive Principle:
Principle #40Composite materials

4Reliability

If chromate treatment time is extended to improve corrosion resistance, then corrosion resistance is improved, but manufacturing time increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmanufacturing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent optimizes the chromate treatment parameters including time, temperature, and solution composition to achieve the required corrosion resistance with minimized treatment duration, balancing performance requirements with manufacturing efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a threaded connection with excellent corrosion resistance, as evidenced by a white rust occurrence area ratio less than 50% after 300 hours of a salt spray test, maintaining galling resistance and sealability.

Implementation Method 1

a Zn—Ni alloy plating layer is formed on at least one of the pin-side contact surface and the box-side contact surface by electroplating

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 2

a chromate coating is formed on the Zn—Ni alloy plating layer. The chromate coating formation step includes a chromate treatment step and a drying step after the chromate treatment step

Methodology Applied
Scientific EffectChromate treatment: Chemical Vapour Deposition

Data Source

PatentUS11408550B2Threaded connection for oil country tubular goods and method for producing threaded connection for oil country tubular goods
Publication Date: 2022.08.09 VALLOUREC MANNESMANN OIL & GAS FRANCE
  • US11408550B2 patent drawing
  • US11408550B2 patent drawing
  • US11408550B2 patent drawing

AI summary

This invention provides a threaded connection for oil country tubular goods that exhibits excellent corrosion resistance and galling resistance, and a method for producing the threaded connection for oil country tubular goods. The method includes a Zn—Ni alloy plating layer formation step of forming a Zn—Ni alloy plating layer, and a chromate coating formation step of forming a chromate coating after the Zn—Ni alloy plating layer formation step. The chromate coating formation step includes a chromate treatment step and a drying step. The chromate coating formation step satisfy one or more conditions selected from the following conditions 1 to 3.Condition 1: stirring speed of the chromating solution in the chromate treatment step: a linear speed of 0.5 m/s or more;Condition 2: chromate treatment time in the chromate treatment step: less than 50 seconds; andCondition 3: drying temperature in the drying step: 60° C. or less.