OELD Second Electrode Calcium Oxide Diffusion Barrier

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Solution Overview

Problem

Organic electroluminescent display devices face issues with moisture absorption and calcium diffusion, leading to reduced lifespan and display quality due to poor adhesion between calcium and aluminum layers, and foreign substances causing short-circuits during the formation of the organic light emitting layer.

Innovation Solution

A dual panel type OELD device is manufactured with a second electrode having a triple-layered structure, including a calcium-diffusion-preventing layer, a low resistance material, and a moisture-absorbing material, and a calcium oxide layer is formed on the second electrode to prevent diffusion and enhance adhesion, along with a patterned spacer to maintain electrical connection and cell gap.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a calcium layer is used as moisture absorbent, then moisture absorption function is improved, but calcium diffuses into aluminum layer causing reduced adhesion and device lifespan

Engineering Contradiction:
Improvemoisture absorptionVSAvoiddevice lifespan
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

An aluminum oxide layer is introduced as an intermediary barrier between the calcium layer and aluminum layer. This oxide layer prevents calcium atoms from diffusing into the aluminum layer while allowing the calcium layer to maintain its moisture absorption function, thus resolving the contradiction between moisture absorption and device reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The second electrode is designed as a composite structure with multiple layers including calcium, aluminum, and aluminum oxide. This composite structure combines the moisture absorption capability of calcium with the diffusion barrier properties of aluminum oxide, achieving both improved moisture absorption and maintained device lifespan

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If foreign substances are present during organic light emitting layer formation, then manufacturing complexity is reduced, but short-circuits occur between electrodes

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidelectrical connection stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The aluminum oxide layer is formed beforehand on the aluminum layer to create a protective barrier. This pre-formed barrier prevents foreign substances from causing short-circuits during the organic light emitting layer formation process, maintaining both manufacturing simplicity and electrical connection reliability

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents calcium diffusion, absorbs moisture, and reduces short-circuits, thereby improving the lifespan and display quality of the OELD device while maintaining efficient electrical connection.

Implementation Method 1

forming a calcium oxide layer on the second electrode to prevent diffusion and enhance adhesion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

forming a moisture-absorbing layer on the calcium oxide layer

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS8018143B2Organic electroluminescent display device and method of manufacturing the same
Publication Date: 2011.09.13 LG DISPLAY CO LTD
  • US8018143B2 patent drawing
  • US8018143B2 patent drawing
  • US8018143B2 patent drawing

AI summary

A method of manufacturing an organic electroluminescent display device includes forming a first electrode on a first substrate including a plurality of pixel regions; forming a patterned spacer on the first electrode in the pixel region; forming an organic light emitting layer on the first electrode in the pixel region and on the patterned spacer; forming a second electrode on the organic light emitting layer; forming a calcium oxide layer on the second electrode; forming a moisture-absorbing layer on the calcium oxide layer; forming a driving thin film transistor on a second substrate; and forming a connection electrode connected to the driving thin film transistor, the connection electrode contacting the second electrode on the patterned spacer.