Optical Emission Spectroscopy for Etching Monitoring

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current etching methods for semiconductor layers face challenges in accurately monitoring partial etching, especially at high pressures, due to the lack of correlation between emission signals and etch amounts, leading to variability and inefficiency in semiconductor processing.

Innovation Solution

The use of optical emission spectroscopy (OES) with signal integration and actinometry, involving existing inert gases, to non-invasively monitor the etching process, allowing for precise control of the plasma discharge based on integrated emission intensity compared to reference values, ensuring accurate partial etching of semiconductor layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional optical emission spectroscopy is used to monitor etching, then real-time monitoring is achieved, but the emission signals do not correlate with etch amounts leading to measurement inaccuracy

Engineering Contradiction:
Improvemeasurement accuracy of etch amountVSAvoidcorrelation between emission signals and etch amounts
Core Design Contradiction:
Measurement precisionVSLoss of information

Solution Approach 1:

The patent introduces an inert gas as an intermediary substance that emits optical signals during the etching process. This intermediary allows the monitoring system to indirectly measure etch progress through the emission intensity of the inert gas, which correlates with the amount of etching performed, thereby solving the lack of direct correlation between conventional emission signals and etch amounts

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the parameter being monitored from general plasma emission signals to the specific emission intensity of an inert gas added to the process. By monitoring the inert gas emission parameter, the system achieves accurate correlation with etch amounts, transforming an uncorrelated measurement into a precise monitoring method

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If dry etching is used to penetrate constrained trenches, then better pattern transfer is achieved, but undesired etching of adjacent structures still occurs

Engineering Contradiction:
Improvepattern transfer qualityVSAvoidundesired etching of adjacent structures
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent implements a feedback control system where the optical emission intensity of the inert gas is continuously monitored during etching. When the emission intensity reaches a predetermined threshold corresponding to the desired etch depth, the system automatically stops the etching process. This feedback mechanism enables precise control of etch depth, achieving good pattern transfer while preventing over-etching of adjacent structures

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent introduces dynamic control of the etching process by continuously adjusting the process based on real-time emission monitoring. The etching process transitions from a static, predetermined duration to a dynamic process that adapts to actual etch progress, allowing precise termination at the target depth while protecting adjacent structures

Inventive Principle:
Principle #15Dynamics

3Manufacturing precision

If partial etching is performed to remove small thickness, then layer thickness is precisely controlled, but monitoring accuracy deteriorates at high pressures

Engineering Contradiction:
Improvelayer thickness controlVSAvoidmonitoring accuracy at high pressures
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The patent uses an inert gas as an intermediary that provides a strong, measurable emission signal even at high pressures where conventional etch byproducts may not emit detectable signals. The inert gas emission serves as a reliable mediator for monitoring partial etching progress, maintaining measurement accuracy across different pressure conditions

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the monitoring parameter from weak conventional emission signals to the strong emission intensity of the inert gas. This parameter change enables accurate detection of small thickness changes in partial etching, even at high pressures where signal detection is typically problematic

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables precise and efficient partial etching of semiconductor layers, reducing variability and improving semiconductor processing by correlating emission signals with etch amounts, even at pressures greater than 1 Torr, thus enhancing the quality and consistency of semiconductor devices.

Implementation Method 1

striking a plasma discharge

Methodology Applied
Scientific EffectPlasma discharge: Plasma

Implementation Method 2

ionize a gas mixture with the plasma subsystem

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

measuring the intensity of emission from a reaction of plasma effluents with the layer

Methodology Applied
Scientific EffectOptical emission spectroscopy: Luminescence

Data Source

PatentUS10541184B2Optical emission spectroscopic techniques for monitoring etching
Publication Date: 2020.01.21 APPLIED MATERIALS INC
  • US10541184B2 patent drawing
  • US10541184B2 patent drawing
  • US10541184B2 patent drawing

AI summary

Embodiments may include a method of etching. The method may also include flowing a gas mixture through a plasma discharge to form plasma effluents. The method may further include flowing the plasma effluents through a plurality of apertures to a layer on a substrate. The layer may have a first thickness. In addition, the method may include etching the layer with the plasma effluents. The method may also include measuring the intensity of emission from a reaction of plasma effluents with the layer. The method may further include summing the intensity of the emission while the plasma effluents are being flowed to the layer to obtain an integrated intensity. The method may then include comparing the integrated intensity to a reference value corresponding to a target etch thickness. The method may include extinguishing the plasma discharge when the integrated intensity is equal to or greater than the reference value.