Oil-Absorbent Polymer Particles for Studless Tire Ice Traction

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Solution Overview

Problem

Studless tires face challenges in improving both on-ice performance and rolling resistance performance simultaneously, with existing technologies not effectively addressing these requirements.

Innovation Solution

A rubber composition for studless tires is developed, comprising natural rubber, polybutadiene rubber, and oil-absorbent polymer particles with specific properties, including a glass transition temperature of −70 to −20° C. and oil absorption of 100 to 1,500 ml/100 g, blended with oil, to enhance traction and reduce rolling resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional oil absorbents are used to retain process oil, then rolling resistance performance is improved, but on-ice performance is not improved

Engineering Contradiction:
Improverolling resistanceVSAvoidon-ice performance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent changes the parameters of the oil absorbent by specifying a glass transition temperature range of -70 to -20°C and oil absorption capacity of 100 to 1,500 ml/100g. These parameter changes enable the oil absorbent to provide both low-temperature flexibility for on-ice performance and oil retention for rolling resistance performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite material system combining natural rubber, polybutadiene rubber, and specifically designed oil-absorbent polymer particles. This composite structure allows the different components to work synergistically, with the oil-absorbent particles providing both the needed flexibility and oil retention properties.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If polymer with high oil affinity is used as oil absorbent, then oil retention is improved, but on-ice performance and rolling resistance performance are not improved

Engineering Contradiction:
Improveoil retentionVSAvoidon-ice performance and rolling resistance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent specifies precise parameter ranges for the oil-absorbent polymer particles, including glass transition temperature (-70 to -20°C), oil absorption capacity (100 to 1,500 ml/100g), and molecular weight distribution (less than 3.0). These parameter changes ensure the polymer provides both oil retention and the necessary low-temperature performance characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates local quality differences within the rubber composition by incorporating oil-absorbent polymer particles with specific properties into the rubber matrix. The particles have high oil affinity locally while the overall composition maintains the flexibility needed for on-ice performance through the controlled glass transition temperature of the polymer particles.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The rubber composition effectively improves on-ice performance and rolling resistance performance while maintaining abrasion resistance, with the oil-absorbent polymer particles forming a micro-flexible phase that enhances adhesion to icy surfaces and reduces heat generation.

Implementation Method 1

oil-absorbent polymer particles having a glass transition temperature of −70 to −20° C., formed from a polymer whose molecular weight distribution is less than 3.0, and having an oil absorption of 100 to 1,500 ml/100 g

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

the oil-absorbent polymer particles forming a micro-flexible phase that enhances adhesion to icy surfaces

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11072695B2Rubber composition for studless tire and studless tire
Publication Date: 2021.07.27 TOYO TIRE CORP

AI summary

A rubber composition for a studless tire according to an embodiment includes a rubber component containing a natural rubber and a polybutadiene rubber; oil-absorbent polymer particles having a glass transition temperature of −70 to −20° C., formed from a polymer whose molecular weight distribution is less than 3.0, and having an oil absorption of 100 to 1,500 ml/100 g; and an oil. The content of the oil-absorbent polymer particles is 0.5 to 25 parts by mass per 100 parts by mass of the rubber component. As a result, on-ice performance and rolling resistance performance can be improved.